(1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene

Base Information

Chemical Name:(1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene
CAS No.:72658-10-7
Molecular Formula:C10H22 O2 Si
Molecular Weight:202.369
Hs Code.:2931900090
European Community (EC) Number:679-538-9
Nikkaji Number:J451.355J,J701.686G
Wikidata:Q76416462
Mol file:72658-10-7.mol

Synonyms:(1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene;72658-10-7;trimethyl-[(E)-1-[(2-methylpropan-2-yl)oxy]prop-1-enoxy]silane;(E)-((1-(tert-Butoxy)prop-1-en-1-yl)oxy)trimethylsilane;OJYHIAHTMZIVKY-CMDGGOBGSA-N;MFCD11114561;AKOS015838080;B3298;1-(Trimethylsiloxy)-1-tert-butoxy-1-propene;(1E)-1-tert-butoxy-1-(trimethylsiloxy)propene;(E)-1-tert-Butoxy-1-(trimethylsiloxy)propene

Suppliers and Price of (1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene
100mg
$ 65.00

TCI Chemical
(1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene >92.0%(GC)
5g
$ 490.00

TCI Chemical
(1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene >92.0%(GC)
1g
$ 165.00

Chem-Impex
(1ε)-1-tert-Butoxy-1-(trimethylsilyloxy)propene,92%(GC) 92%(GC)
5G
$ 538.72

Chem-Impex
(1ε)-1-tert-Butoxy-1-(trimethylsilyloxy)propene,92%(GC) 92%(GC)
1G
$ 160.16

Biosynth Carbosynth
(1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene
1 g
$ 127.20

Biosynth Carbosynth
(1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene
500 mg
$ 70.00

Biosynth Carbosynth
(1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene
2 g
$ 220.80

Biosynth Carbosynth
(1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene
5 g
$ 440.40

Biosynth Carbosynth
(1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene
10 g
$ 748.80

Total 9 raw suppliers

Chemical Property of (1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene

Chemical Property:

Vapor Pressure:0.656mmHg at 25°C
Refractive Index:1.426
Boiling Point:193.2°C at 760 mmHg
Flash Point:57.2°C
PSA：18.46000
Density:0.859g/cm³
LogP:3.51430
Storage Temp.:0-10°C
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:202.138906475
Heavy Atom Count:13
Complexity:184

Purity/Quality:

97% ^*data from raw suppliers

(1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC=C(OC(C)(C)C)O[Si](C)(C)C
Isomeric SMILES:C/C=C(\OC(C)(C)C)/O[Si](C)(C)C

Technology Process of (1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene

There total 4 articles about (1E)-1-tert-Butoxy-1-(trimethylsilyloxy)propene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 75-77-4
chloro-trimethyl-silane

: 20487-40-5
tert-butyl propionate

: 72658-10-7
tert-butyl trimethylsilyl methyl ketene acetal

Guidance literature:: tert-butyl propionate; With n-butyllithium; diisopropylamine; In cyclohexane; cyclopentyl methyl ether; at 0 ℃; for 0.833333h; Inert atmosphere;

chloro-trimethyl-silane; In cyclohexane; cyclopentyl methyl ether; at 0 ℃; for 2.25h; optical yield given as %de; Inert atmosphere;
DOI:10.1021/ja2066829

Reference yield: 69.0%

: 75-77-4
chloro-trimethyl-silane

: 20487-40-5
tert-butyl propionate

: 57482-70-9
tert-butyl 2-(trimethylsilyl)propionate

: 72658-10-7
tert-butyl trimethylsilyl methyl ketene acetal

Guidance literature:: tert-butyl propionate; With n-butyllithium; diisopropylamine; In hexane; at 0 - 5 ℃; for 0.75h;

chloro-trimethyl-silane; In hexane; at 0 - 5 ℃; for 1.58333h; Further stages.;
DOI:10.1021/jo701456t

Reference yield:

: 75-77-4
chloro-trimethyl-silane

: 1663-39-4,25232-27-3
tert-Butyl acrylate

: 72658-10-7
tert-butyl trimethylsilyl methyl ketene acetal

Guidance literature:: tert-Butyl acrylate; With tris(triphenylphosphine)rhodium(l) chloride; diethylzinc; In tetrahydrofuran; at 0 ℃; for 0.0833333h; Inert atmosphere; Schlenk technique;

chloro-trimethyl-silane;
DOI:10.3762/bjoc.12.157