(Z)-2-(1,2-diphenylprop-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Base Information

Chemical Name:(Z)-2-(1,2-diphenylprop-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS No.:1398771-32-8
Molecular Formula:C₂₁H₂₅BO₂
Molecular Weight:320.239
Hs Code.:

Synonyms:(Z)-2-(1,2-diphenylprop-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Suppliers and Price of (Z)-2-(1,2-diphenylprop-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (Z)-2-(1,2-diphenylprop-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (Z)-2-(1,2-diphenylprop-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

There total 9 articles about (Z)-2-(1,2-diphenylprop-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 501-65-5
diphenyl acetylene

: 73183-34-3
bis(pinacol)diborane

: 74-88-4
methyl iodide

: 1398771-32-8
(Z)-2-(1,2-diphenylprop-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: bis(pinacol)diborane; With Tri(p-tolyl)phosphine; copper(l) chloride; sodium t-butanolate; In tetrahydrofuran; toluene; at 20 ℃; for 0.0833333h; Inert atmosphere;

diphenyl acetylene; methyl iodide; In tetrahydrofuran; toluene; at 60 ℃; for 24h; Reagent/catalyst; Solvent; Temperature; Concentration; stereoselective reaction; Inert atmosphere;
DOI:10.1021/ja307670k

Reference yield: 39.0%

: bis(pinacolato)diborane

: 501-65-5
diphenyl acetylene

: 80-48-8
methyl p-toluene sulfonate

: 1398771-32-8
(Z)-2-(1,2-diphenylprop-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With potassium tert-butylate; copper diacetate; tricyclohexylphosphine; In tetrahydrofuran; N,N-dimethyl-formamide; toluene; at 50 ℃; for 44h; stereoselective reaction; Schlenk technique;
DOI:10.1021/ol4001526

Reference yield:

: 54288-47-0
N'-(1,2-diphenylpropylidene)-4-methylbenzenesulfonohydrazide

: 73183-34-3
bis(pinacol)diborane

: (E)-1-(4',4',5',5'-tetramethyl-1',3',2'-dioxaborolan-2'-yl)-1,2-diphenyl-1-propene

: 1398771-32-8
(Z)-2-(1,2-diphenylprop-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With 2,5-Dimethyl-1,4-benzoquinone; palladium diacetate; sodium hydride; tri(m-tolyl)phosphine; In toluene; at 90 ℃; for 10h; Overall yield = 66 percent; Overall yield = 63.4 mg; Inert atmosphere; Schlenk technique;
DOI:10.1021/jacs.1c02331