[1,4-bis(3,5-ditrifluoromethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]dimethylpalladium(II)

Base Information

Chemical Name:[1,4-bis(3,5-ditrifluoromethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]dimethylpalladium(II)
CAS No.:609810-40-4
Molecular Formula:C₂₂H₁₈F₁₂N₂Pd
Molecular Weight:644.799
Hs Code.:

Synonyms:[1,4-bis(3,5-ditrifluoromethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]dimethylpalladium(II)

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Chemical Property of [1,4-bis(3,5-ditrifluoromethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]dimethylpalladium(II)

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Technology Process of [1,4-bis(3,5-ditrifluoromethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]dimethylpalladium(II)

There total 1 articles about [1,4-bis(3,5-ditrifluoromethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]dimethylpalladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 400608-66-4
N,N’-bis-(3,5di(trifluoromethyl)phenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene

: 63936-77-6
(1,5-cyclooctadiene)dimethylpalladium(II)

: 609810-40-4
[1,4-bis(3,5-ditrifluoromethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]dimethylpalladium(II)

Guidance literature:: In diethyl ether; Schlenk flask charged with (COD)PdMe2 and the ligand, cooled to 0 °C, and Et2O transferred via cannula onto solids; suspn. stirred for 1 h at 0 °C and warmed to room temp.; solid filtered, washed with cold Et2O and pentane, and dried in vacuo; elem. anal.;
DOI:10.1021/om0303294

Reference yield:

: tetrafluoroboric acid

: 609810-40-4
[1,4-bis(3,5-ditrifluoromethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]dimethylpalladium(II)

: 7732-18-5
water

: 80937-33-3
oxygen

: bis[(1,4-bis(3,5-ditrifluoromethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene)(μ-hydroxo)palladium(II)] tetrafluoroborate

: 7440-05-3
palladium

Guidance literature:: With benzene or benzene-d6; D₂O; In water; byproducts: methane or CH3D, biphenyl; dry trifluoroethanol-d3 added to NMR tube contg. the Pd complex; aq. HBF4 added; mixt. shaken to form clear soln.; D2O added; tube frozen at -78°C, evacuated and filled with 1 atm of O2; after thawing, benzen e added; mixt. kept at room temp.; NMR anal.; Kinetics;
DOI:10.1021/om0303294

Reference yield:

: tetrafluoroboric acid

: 609810-40-4
[1,4-bis(3,5-ditrifluoromethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]dimethylpalladium(II)

: 7732-18-5
water

: 609810-33-5
aqua[1,4-bis(3,5-ditrifluoromethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]methylpalladium(II) tetrafluoroborate

Guidance literature:: In water; dry trifluoroethanol-d3 added to NMR tube contg. the Pd complex; aq. HBF4 added; mixt. shaken to form clear soln.; not isolated; NMR anal.;
DOI:10.1021/om0303294