(1-benzyloxymethyl-cyclohexa-2,5-dienylmethoxy)-tert-butyl-dimethyl-silane

Base Information

Chemical Name:(1-benzyloxymethyl-cyclohexa-2,5-dienylmethoxy)-tert-butyl-dimethyl-silane
CAS No.:637362-45-9
Molecular Formula:C₂₁H₃₂O₂Si
Molecular Weight:344.569
Hs Code.:

(1-benzyloxymethyl-cyclohexa-2,5-dienylmethoxy)-<i>tert</i>-butyl-dimethyl-silane

Synonyms:(1-benzyloxymethyl-cyclohexa-2,5-dienylmethoxy)-tert-butyl-dimethyl-silane

Suppliers and Price of (1-benzyloxymethyl-cyclohexa-2,5-dienylmethoxy)-tert-butyl-dimethyl-silane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1-benzyloxymethyl-cyclohexa-2,5-dienylmethoxy)-tert-butyl-dimethyl-silane

Chemical Property:

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Technology Process of (1-benzyloxymethyl-cyclohexa-2,5-dienylmethoxy)-tert-butyl-dimethyl-silane

There total 1 articles about (1-benzyloxymethyl-cyclohexa-2,5-dienylmethoxy)-tert-butyl-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 74269-63-9
(1-Benzyloxymethyl-cyclohexa-2,5-dienyl)-methanol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 637362-45-9
(1-benzyloxymethyl-cyclohexa-2,5-dienylmethoxy)-tert-butyl-dimethyl-silane

Guidance literature:: With 1H-imidazole; dmap; In dichloromethane; N,N-dimethyl-formamide; at 20 ℃; for 10h;
DOI:10.1016/j.tetlet.2003.09.215

Reference yield: 94.0%

: 637362-45-9
(1-benzyloxymethyl-cyclohexa-2,5-dienylmethoxy)-tert-butyl-dimethyl-silane

: 637362-46-0
[1-[(tert-butyldimethylsilyloxy)methyl]cyclohexa-2,5-dienyl]methanol

Guidance literature:: With ammonia; lithium; In tetrahydrofuran; at -20 ℃; for 0.333333h;
DOI:10.1016/j.tetlet.2003.09.215

Reference yield:

: 637362-45-9
(1-benzyloxymethyl-cyclohexa-2,5-dienylmethoxy)-tert-butyl-dimethyl-silane

: 637362-52-8
3a-benzenesulfonyl-6a-(tert-butyl-dimethyl-silanyloxymethyl)-1,3a,3b,4,6a,6b-hexahydro-2H-cyclopropa[de]naphthalen-3-one

Guidance literature:: Multi-step reaction with 7 steps

1: 94 percent / Li; liq. NH₃ / tetrahydrofuran / 0.33 h / -20 °C

2: 90 percent / Dess-Martin reagent; NaHCO₃ / CH₂Cl₂ / 2 h / 20 °C

3: 99 percent / t-BuOK / tetrahydrofuran / -78 - 0 °C

4: 88 percent / Mg / 0 °C

5: 92 percent / n-BuLi / tetrahydrofuran / 0 °C

6: 90 percent / TsN₃; TEA / acetonitrile / 6 h / 0 - 20 °C

7: dimethyl-diisopropyl-bisoxazoline derivative / CuOTf / toluene / 0.5 h / 20 °C

With n-butyllithium; 4-toluenesulfonyl azide; dimethyl-diisopropyl-bisoxazoline derivative; TEA; potassium tert-butylate; ammonia; lithium; sodium hydrogencarbonate; Dess-Martin periodane; magnesium; copper(I) triflate; In tetrahydrofuran; dichloromethane; toluene; acetonitrile; 2: Dess-Martin oxidation / 3: Horner-Wadsworth-Emmons reaction;
DOI:10.1016/j.tetlet.2003.09.215