methyl 2-chloro-4-(1-(1,2,3,4-tetrahydro-1,1,4,4,6-pentamethylnaphthalen-7-yl)vinyl)benzoate

Base Information

Chemical Name:methyl 2-chloro-4-(1-(1,2,3,4-tetrahydro-1,1,4,4,6-pentamethylnaphthalen-7-yl)vinyl)benzoate
CAS No.:1403326-68-0
Molecular Formula:C₂₅H₂₉ClO₂
Molecular Weight:396.957
Hs Code.:

Synonyms:methyl 2-chloro-4-(1-(1,2,3,4-tetrahydro-1,1,4,4,6-pentamethylnaphthalen-7-yl)vinyl)benzoate

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Chemical Property of methyl 2-chloro-4-(1-(1,2,3,4-tetrahydro-1,1,4,4,6-pentamethylnaphthalen-7-yl)vinyl)benzoate

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Technology Process of methyl 2-chloro-4-(1-(1,2,3,4-tetrahydro-1,1,4,4,6-pentamethylnaphthalen-7-yl)vinyl)benzoate

There total 15 articles about methyl 2-chloro-4-(1-(1,2,3,4-tetrahydro-1,1,4,4,6-pentamethylnaphthalen-7-yl)vinyl)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 1403326-88-4
methyl 2-chloro-4-(1-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)carbonyl)benzoate

: 19493-09-5
Methylenetriphenylphosphorane

: 1403326-68-0
methyl 2-chloro-4-(1-(1,2,3,4-tetrahydro-1,1,4,4,6-pentamethylnaphthalen-7-yl)vinyl)benzoate

Guidance literature:: In tetrahydrofuran; at 20 ℃;
DOI:10.1002/cmdc.201200319

Reference yield:

: 110-03-2
2,5-dimethyl-2,5-hexanediol

: 1403326-68-0
methyl 2-chloro-4-(1-(1,2,3,4-tetrahydro-1,1,4,4,6-pentamethylnaphthalen-7-yl)vinyl)benzoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: hydrogenchloride / water

2.1: aluminum (III) chloride

3.1: aluminum (III) chloride / dichloromethane / 0.33 h / 20 °C / Reflux

3.3: 20 °C

With hydrogenchloride; aluminum (III) chloride; In dichloromethane; water;
DOI:10.1002/cmdc.201200319

Reference yield:

: 6683-48-3
1,1,4,4,6-pentamethyl-1,2,3,4-tetrahydronaphthalene

: 19493-09-5
Methylenetriphenylphosphorane

: 299173-15-2
4-carbomethoxy-3-iodobenzoyl chloride

: 1403326-68-0
methyl 2-chloro-4-(1-(1,2,3,4-tetrahydro-1,1,4,4,6-pentamethylnaphthalen-7-yl)vinyl)benzoate

: 1403326-70-4
methyl 2-iodo-4-(1-(1,2,3,4-tetrahydro-1,1,4,4,6-pentamethylnaphthalen-7-yl)vinyl)benzoate

Guidance literature:: 1,1,4,4,6-pentamethyl-1,2,3,4-tetrahydronaphthalene; 4-carbomethoxy-3-iodobenzoyl chloride; With aluminum (III) chloride; In dichloromethane; at 20 ℃; for 0.333333h; Reflux;

With hydrogenchloride; water; In dichloromethane;

Methylenetriphenylphosphorane; In tetrahydrofuran; at 20 ℃; Overall yield = 32 %; Overall yield = 0.3502 g;
DOI:10.1002/cmdc.201200319