10-{4-[(trimethylsilyl)ethynyl]phenyl}-10H-phenothiazine

Base Information

Chemical Name:10-{4-[(trimethylsilyl)ethynyl]phenyl}-10H-phenothiazine
CAS No.:1616858-37-7
Molecular Formula:C₂₃H₂₁NSSi
Molecular Weight:371.578
Hs Code.:

Synonyms:10-{4-[(trimethylsilyl)ethynyl]phenyl}-10H-phenothiazine

Suppliers and Price of 10-{4-[(trimethylsilyl)ethynyl]phenyl}-10H-phenothiazine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 10-{4-[(trimethylsilyl)ethynyl]phenyl}-10H-phenothiazine

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Technology Process of 10-{4-[(trimethylsilyl)ethynyl]phenyl}-10H-phenothiazine

There total 6 articles about 10-{4-[(trimethylsilyl)ethynyl]phenyl}-10H-phenothiazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1066-54-2
trimethylsilylacetylene

: 262861-84-7
10-(4-iodophenyl)-10-H-phenothiazine

: 1616858-37-7
10-{4-[(trimethylsilyl)ethynyl]phenyl}-10H-phenothiazine

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine; at 20 ℃; for 16h; Inert atmosphere;
DOI:10.1002/chem.201404372

Reference yield: 93.0%

: 1066-54-2
trimethylsilylacetylene

: 63524-03-8
10-(4 -bromophenyl)-10H-phenothiazine

: 1616858-37-7
10-{4-[(trimethylsilyl)ethynyl]phenyl}-10H-phenothiazine

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; triphenylphosphine; for 15h; Inert atmosphere; Reflux;
DOI:10.1021/ja5040073

Reference yield:

: 92-84-2
10H-phenothiazine

: 1616858-37-7
10-{4-[(trimethylsilyl)ethynyl]phenyl}-10H-phenothiazine

Guidance literature:: Multi-step reaction with 2 steps

1: potassium carbonate; copper(ll) sulfate pentahydrate / 15 h / 220 °C / Inert atmosphere

2: copper(l) iodide; triphenylphosphine; triethylamine; bis-triphenylphosphine-palladium(II) chloride / 15 h / Inert atmosphere; Reflux

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; copper(ll) sulfate pentahydrate; potassium carbonate; triethylamine; triphenylphosphine; 1: |Ullmann Condensation / 2: |Sonogashira Cross-Coupling;
DOI:10.1021/ja5040073