1,4-dimethoxycyclohexane

Base Information

• Chemical Name: 1,4-dimethoxycyclohexane
• CAS No.: 100249-54-5
• Molecular Formula: C₈H₁₆O₂
• Molecular Weight: 144.214
• Mol file: 100249-54-5.mol

Synonyms:1,4-dimethoxycyclohexane

Chemical Property of 1,4-dimethoxycyclohexane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,4-dimethoxycyclohexane

There total 6 articles about 1,4-dimethoxycyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1,4-dimethoxybezene (150-78-7) → 1,4-dimethoxycyclohexane (100249-54-5)

Guidance literature:

With Ti₈O₈⁽¹⁴⁺⁾*6C₈H₄O₄^(2-)*4O^(2-)*3.3Li⁽¹⁺⁾*0.7Co⁽²⁺⁾*0.7C₄H₈O*0.7H^(1-); hydrogen; In neat (no solvent); at 160 ℃; for 18h; under 37503.8 Torr;

DOI:10.1021/jacs.7b11241

Reference yield: 97.0%

→ 1,4-dimethoxycyclohexane (100249-54-5)

Guidance literature:

Reference yield:

4-methoxycyclohexan-1-ol (18068-06-9) + methyl iodide (74-88-4) → 1,4-dimethoxycyclohexane (100249-54-5)

Guidance literature:

In N,N-dimethyl-formamide; Yield given; Ambient temperature;

upstream raw materials:

1,4-dimethoxybezene

cyclohexane-1,4-diol

methyl iodide

cis-1,4-cyclohexanediol

Refernces

• 1、 Chen, Lu,Van Muyden, Antoine P.,Cui, Xinjiang,Laurenczy, Gabor,Dyson, Paul J.. "Selective hydrogenation of lignin-derived compounds under mild conditions". . p. 3069 - 3073. Retrieved 2020/06/17.
• 2、 Curulli, Antonella,Feroci, Marta,Inesi, Achille. "REACTIVITY OF ELECTROGENERATED SUPEROXIDE ION. PART 3. Oxidative cleavage and reduction of some cyclohexanones.". . p. 3320 - 3338. Retrieved 2007/10/02.