Technology Process of C19H28O3S2
There total 2 articles about C19H28O3S2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C9H16OS2;
With
tert.-butyl lithium;
In
tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; pentane;
at -78 ℃;
for 0.166667h;
Inert atmosphere;
(S)-benzyl glycidyl ether;
In
tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; pentane;
at -78 ℃;
for 1h;
Inert atmosphere;
With
ammonium chloride;
In
tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; water; pentane;
DOI:10.1002/ejoc.201101549
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: tetra-(n-butyl)ammonium iodide; sodium hydride / N,N-dimethyl-formamide / 2 h / 0 - 25 °C / Inert atmosphere
2.1: tert.-butyl lithium / tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; pentane / 0.17 h / -78 °C / Inert atmosphere
2.2: 1 h / -78 °C / Inert atmosphere
With
tert.-butyl lithium; tetra-(n-butyl)ammonium iodide; sodium hydride;
In
tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide; pentane;
DOI:10.1002/ejoc.201101549
- Guidance literature:
-
With
manganese(IV) oxide;
In
dichloromethane;
at 25 ℃;
for 10h;
optical yield given as %de;
diastereoselective reaction;
Inert atmosphere;
DOI:10.1002/ejoc.201101549