bis(diphenylphosphino)ethane-platinum(II) diacetylide

Base Information

Chemical Name:bis(diphenylphosphino)ethane-platinum(II) diacetylide
CAS No.:56179-44-3
Molecular Formula:C₃₀H₂₆P₂Pt
Molecular Weight:643.564
Hs Code.:

Synonyms:bis(diphenylphosphino)ethane-platinum(II) diacetylide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bis(diphenylphosphino)ethane-platinum(II) diacetylide

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

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Technology Process of bis(diphenylphosphino)ethane-platinum(II) diacetylide

There total 3 articles about bis(diphenylphosphino)ethane-platinum(II) diacetylide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 83095-83-4,14647-25-7
[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)]

: 74-86-2,25067-58-7
acetylene

: 56179-44-3
bis(diphenylphosphino)ethane-platinum(II) diacetylide

Guidance literature:: With Et₂NH; copper(l) iodide; In tetrahydrofuran; (Ar); CuI was added to suspn. of Pt complex in THF/Et2NH at 0°C; ethyne was bubbled through mixt. for 2 h; solvent removed (vac.); residue dissolved in CH2Cl2; washed (H2O); org. phase dried (MgSO4); filtered; filtrate passed through alumina; solvent removed; recrystd. (CH2Cl2/ether); dried (vac.); elem. anal.;
DOI:10.1021/om049690w

Reference yield:

: 83095-83-4,14647-25-7
[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)]

: 1675-61-2
di(ethynyl)dimethylstannane

: 56179-44-3
bis(diphenylphosphino)ethane-platinum(II) diacetylide

: 753-73-1
dimethyltin dichloride

Guidance literature:: In tetrahydrofuran; addn. of Me2Sn(CCH)2 to a soln. of (Ph2PC2H4PPh2)PtCl2 in THF and refluxing for 4 h (N2); concn. of the clear soln. up to beginning turbidity, addn. of hexane orpentane and cooling on an ice bath, filtering off the ppt., repeated washings with hexane and drying at room temp. in vacuo;

Reference yield:

: 83095-83-4,14647-25-7
[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)]

: 1112-00-1
trimethylstannylacetylene

: 56179-44-3
bis(diphenylphosphino)ethane-platinum(II) diacetylide

: 1066-45-1
trimethyltin(IV)chloride

Guidance literature:: In tetrahydrofuran; addn. of Me3SnCCH to a soln. of (Ph2PC2H4PPh2)PtCl2 in THF and refluxing for 12 h (N2); concn. of the clear soln. up to beginning turbidity, addn. of hexane orpentane and cooling on an ice bath, filtering off the ppt., repeated washings with hexane and drying at room temp. in vacuo;