O,O-diethyl O-4-trimethylstannylphenyl phosphate

Base Information

Chemical Name:O,O-diethyl O-4-trimethylstannylphenyl phosphate
CAS No.:866927-68-6
Molecular Formula:C₁₃H₂₃O₄PSn
Molecular Weight:393.007
Hs Code.:

Synonyms:O,O-diethyl O-4-trimethylstannylphenyl phosphate

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Chemical Property of O,O-diethyl O-4-trimethylstannylphenyl phosphate

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Technology Process of O,O-diethyl O-4-trimethylstannylphenyl phosphate

There total 3 articles about O,O-diethyl O-4-trimethylstannylphenyl phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

: 16498-01-4
O,O-diethyl O-4-bromophenyl phosphate

: 1066-45-1
trimethyltin(IV)chloride

: 866927-68-6
O,O-diethyl O-4-trimethylstannylphenyl phosphate

: 2510-86-3
O,O-diethyl O-phenyl phosphate

: 934-56-5
trimethyl(phenyl)stannane

: 661-69-8
hexamethyldistannane

Guidance literature:: With sodium; In ammonia; Irradiation (UV/VIS); (CH3)3SnCl was dissolved in ammonia, Na metal was added until a blue color persisted for 5 min, when the blue color dissapeared, phosphate esterwas added, the mixt. was UV-irradiated with stirring for 1 h; excess of CH3I was added, NH3 was evapd., the residue was treated with water, extd. with ether, washed with aq. satd. soln. of NaCl, dried over MgSO4, recrystd. in ethanol;
DOI:10.1021/om010878e

Reference yield: 28.0%

: 940-00-1
(4-methoxyphenyl)trimethylstannane

: 16643-09-7
trimethylstannyl sodium

: 814-49-3
diethyl chlorophosphate

: 866927-68-6
O,O-diethyl O-4-trimethylstannylphenyl phosphate

Guidance literature:: In dimethyl sulfoxide; byproducts: C6H5OP(O)(OC2H5)2, C6H5OCH3; under N2 or Ar atm.; mixt. of Me3SnNa and trimethyl(4-methoxyphenyl)stannane in DMSO was heated at 110°C for 90 min; diethylchlorophosphate added at room temp.; soln. stirred for 24 h; mixt. quenched (H2O); extd. (Et2O); ether fraction washed (brine); dried(MgSO4); concd. (vac.); purified by TLC (hexane/EtOAc, 6:4 as eluent);
DOI:10.1016/j.jorganchem.2005.05.023

Reference yield: 26.0%

: 16462-79-6
diethyl (4-iodophenyl) phosphate

: 1066-45-1
trimethyltin(IV)chloride

: 866927-68-6
O,O-diethyl O-4-trimethylstannylphenyl phosphate

: 2510-86-3
O,O-diethyl O-phenyl phosphate

: 934-56-5
trimethyl(phenyl)stannane

: 661-69-8
hexamethyldistannane

Guidance literature:: With sodium; In ammonia; Irradiation (UV/VIS); (CH3)3SnCl was dissolved in ammonia, Na metal was added until a blue color persisted for 5 min, when the blue color dissapeared, phosphate esterwas added, the mixt. was UV-irradiated with stirring for 1 h; excess of CH3I was added, NH3 was evapd., the residue was treated with water, extd. with ether, washed with aq. satd. soln. of NaCl, dried over MgSO4, recrystd. in ethanol;
DOI:10.1021/om010878e