4-iodotetradecachlorotriphenylmethyl radical

Base Information

• Chemical Name: 4-iodotetradecachlorotriphenylmethyl radical
• CAS No.: 79855-17-7
• Molecular Formula: C₁₉Cl₁₄I
• Molecular Weight: 851.456
• Mol file: 79855-17-7.mol

Synonyms:4-iodotetradecachlorotriphenylmethyl radical

Chemical Property of 4-iodotetradecachlorotriphenylmethyl radical

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-iodotetradecachlorotriphenylmethyl radical

There total 2 articles about 4-iodotetradecachlorotriphenylmethyl radical which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-[bis(2,3,4,5,6-pentachlorophenyl)methyl]-2,3,5,6-tetrachlorobenzoic acid (79839-41-1) → 4-iodotetradecachlorotriphenylmethyl radical (79855-17-7) + (tetradecachloro-4-carboxytriphenyl)methyl radical (77212-86-3)

Guidance literature:

With sodium hydroxide; iodine; Yield given. Multistep reaction. Yields of byproduct given; 1.) ether, Me₂SO, 24 h, 2.) 24 h;

DOI:10.1021/jo00341a015

Reference yield:

αH-(Heptadecachloro-4-methyltriphenyl)methane (78227-02-8) → 4-iodotetradecachlorotriphenylmethyl radical (79855-17-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 74.9 percent / 20percent oleum / 90 h / 110 - 120 °C

2: 1.) NaOH, 2.) I₂ / 1.) ether, Me₂SO, 24 h, 2.) 50 min

With sodium hydroxide; sulfuric acid; iodine;

DOI:10.1021/jo00341a015

Reference yield: 98.5%

4-iodotetradecachlorotriphenylmethyl radical (79855-17-7) → 4-Bromotetradecachlorotriphenylmethyl Radical (79855-16-6)

Guidance literature:

With bromine; In tetrachloromethane; for 72h;

DOI:10.1021/jo00341a015

upstream raw materials:

4-[bis(2,3,4,5,6-pentachlorophenyl)methyl]-2,3,5,6-tetrachlorobenzoic acid

αH-(Heptadecachloro-4-methyltriphenyl)methane

Downstream raw materials:

perchlorotriphenylmethyl radical

4-Bromotetradecachlorotriphenylmethyl Radical