1-[bis(2,3,4,5,6-pentachlorophenyl)methyl]-2,3,4,5,6-pentachloro-benze ne

Base Information

• Chemical Name: 1-[bis(2,3,4,5,6-pentachlorophenyl)methyl]-2,3,4,5,6-pentachloro-benze ne
• CAS No.: 4070-01-3
• Molecular Formula: C19HCl15
• Molecular Weight: 760.004
• Mol file: 4070-01-3.mol

Synonyms:1-[bis(2,3,4,5,6-pentachlorophenyl)methyl]-2,3,4,5,6-pentachlorobenzene;

Chemical Property of 1-[bis(2,3,4,5,6-pentachlorophenyl)methyl]-2,3,4,5,6-pentachloro-benze ne

Chemical Property:

• Boiling Point: 655.7°Cat760mmHg
• Flash Point: 344.3°C
• PSA: 0.00000
• Density: 1.847g/cm³
• LogP: 14.66780

Purity/Quality:

99%min ^*data from raw suppliers

PerchlorotriphenylmethylRadical ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Uses: PerchlorotriphenylMethyl Radical is used as a spin probe to study other molecules, including polymers. Stable perchlorinated arylmethyl radical used as a spin probe to study other molecules, including polymers.

Technology Process of 1-[bis(2,3,4,5,6-pentachlorophenyl)methyl]-2,3,4,5,6-pentachloro-benze ne

There total 12 articles about 1-[bis(2,3,4,5,6-pentachlorophenyl)methyl]-2,3,4,5,6-pentachloro-benze ne which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

18-C-6-potassium perchlorotriphenylmethide complex (1/1) → perchlorotriphenylmethyl radical (4070-01-3)

Guidance literature:

With iodine; In dichloromethane; for 4h;

DOI:10.1016/0022-328X(85)80410-1

Reference yield: 92.0%

4-Bromotetradecachlorotriphenylmethyl Radical (79855-16-6) → perchlorotriphenylmethyl radical (4070-01-3)

Guidance literature:

With chlorine; In tetrachloromethane; for 71h;

DOI:10.1021/jo00341a015

Reference yield: 90.0%

perchloro(diphenylmethylene)cyclohexa-1,4-diene (122898-71-9) → perchlorotriphenylmethyl radical (4070-01-3)

Guidance literature:

With copper; In tetrachloromethane; for 48h; Ambient temperature;

DOI:10.1021/jo00280a030

upstream raw materials:

αH-Pentadecachlorotriphenylmethane

4-H-tetradecachlorotriphenylmethyl radical

Tetra-n-butylammonium perchlorotriphenylmethide

4-Bromotetradecachlorotriphenylmethyl Radical

Downstream raw materials:

Perchloro-9-phenylfluorenyl radical

α-hydroperchloro-9-phenylfluorene

αH-Pentadecachlorotriphenylmethane

perchlorofuchsone, perchloro(diphenylmethylene)cyclohexa-2,5-dienone

Refernces

• 1、 Dai, Ya-Zhong,Dong, Bo-Wei,Kao, Yi,Wang, Zi-Yuan,Un, Hio-Ieng,Liu, Zheng,Lin, Zhi-Jun,Li, Liang,Xie, Fang-Bai,Lu, Yang,Xu, Mei-Xing,Lei, Ting,Sun, Yu-Jie,Wang, Jie-Yu,Gao, Song,Jiang, Shang-Da,Pei, Jian. "Chemical Modification toward Long Spin Lifetimes in Organic Conjugated Radicals". . p. 2972 - 2977. Retrieved 2018/09/25.
• 2、 Ballester, Manuel,Pascual, Isabel,Riera, Juan,Castaner, Juan. ""Spin-Charge Exchange" in Allodial Radical Ions, a Novel Intramolecular Single Electron Transfer Equilibrium". . p. 217 - 225. Retrieved 2007/10/02.