fac-W(CO)3(PhC(OH))(Ph₂POCH₂(CH₂OCH₂)2CH₂OPPh₂)

Base Information

Chemical Name:fac-W(CO)3(PhC(OH))(Ph₂POCH₂(CH₂OCH₂)2CH₂OPPh₂)
CAS No.:123188-15-8
Molecular Formula:C₄₀H₃₈O₈P₂W
Molecular Weight:892.534
Hs Code.:

fac-W(CO)3(PhC(OH))(Ph<sub>2</sub>POCH<sub>2</sub>(CH<sub>2</sub>OCH<sub>2</sub>)2CH<sub>2</sub>OPPh<sub>2</sub>)

Synonyms:fac-W(CO)3(PhC(OH))(Ph₂POCH₂(CH₂OCH₂)2CH₂OPPh₂)

Suppliers and Price of fac-W(CO)3(PhC(OH))(Ph₂POCH₂(CH₂OCH₂)2CH₂OPPh₂)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of fac-W(CO)3(PhC(OH))(Ph₂POCH₂(CH₂OCH₂)2CH₂OPPh₂)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of fac-W(CO)3(PhC(OH))(Ph₂POCH₂(CH₂OCH₂)2CH₂OPPh₂)

There total 2 articles about fac-W(CO)3(PhC(OH))(Ph₂POCH₂(CH₂OCH₂)2CH₂OPPh₂) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 75-77-4
chloro-trimethyl-silane

: 91582-42-2
fac-(CO)3W(C(C₆H₅)OLi)(Ph₂POCH₂(CH₂OCH₂)2CH₂OPPh₂)*CH₂Cl₂

: 123188-15-8
fac-W(CO)3(PhC(OH))(Ph₂POCH₂(CH₂OCH₂)2CH₂OPPh₂)

Guidance literature:: With H₂O or CH₃OH; In dichloromethane; byproducts: LiCl; N2 atmosphere; adding (CH3)3SiCl to solution of W-complex in CH2Cl2 (colour of mixture turning to red); stirring for 1h at 10°C; hydrolysis; extraction (H2O); (intermediate not isolated); recrystn. (acetone); elemental analysis;

Reference yield:

: 75-77-4
chloro-trimethyl-silane

: Li⁽¹⁺⁾*[W(CO)3(C(C₆H₅)O)(((C₆H₅)2POCH₂CH₂OCH₂)2)]^(1-)=Li[W(CO)3(C(C₆H₅)O)(((C₆H₅)2POCH₂CH₂OCH₂)2)]

: 123188-15-8
fac-W(CO)3(PhC(OH))(Ph₂POCH₂(CH₂OCH₂)2CH₂OPPh₂)

Guidance literature:: With MeOH; In methanol; the complex was reacted with equimolar amount of Me3SiCl followed by MeOH; solid was isolated;elem.anal.;
DOI:10.1016/S0020-1693(00)81013-0