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Technology Process of [Ni2(((CH3)3CC6H2(S)CH2N(CH3)CH2CH2N(CH3)CH2CH2N(CH3)CH2)2)(μ-benzoato)](perchlorate)

[Ni2(((CH3)3CC6H2(S)CH2N(CH3)CH2CH2N(CH3)CH2CH2N(CH3)CH2)2)(μ-benzoato)](perchlorate)

Base Information Edit
  • Chemical Name:[Ni2(((CH3)3CC6H2(S)CH2N(CH3)CH2CH2N(CH3)CH2CH2N(CH3)CH2)2)(μ-benzoato)](perchlorate)
  • CAS No.:698370-06-8
  • Molecular Formula:C45H69N6Ni2O2S2*ClO4
  • Molecular Weight:1007.04
  • Hs Code.:
  • Mol file:698370-06-8.mol
[Ni<sub>2</sub>(((CH<sub>3</sub>)<sub>3</sub>CC<sub>6</sub>H<sub>2</sub>(S)CH<sub>2</sub>N(CH<sub>3</sub>)CH<sub>2</sub>CH<sub>2</sub>N(CH<sub>3</sub>)CH<sub>2</sub>CH<sub>2</sub>N(CH<sub>3</sub>)CH<sub>2</sub>)<sub>2</sub>)(μ-benzoato)](perchlorate)

Synonyms:[Ni2(((CH3)3CC6H2(S)CH2N(CH3)CH2CH2N(CH3)CH2CH2N(CH3)CH2)2)(μ-benzoato)](perchlorate)

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Chemical Property of [Ni2(((CH3)3CC6H2(S)CH2N(CH3)CH2CH2N(CH3)CH2CH2N(CH3)CH2)2)(μ-benzoato)](perchlorate) Edit
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Technology Process of [Ni2(((CH3)3CC6H2(S)CH2N(CH3)CH2CH2N(CH3)CH2CH2N(CH3)CH2)2)(μ-benzoato)](perchlorate)

There total 1 articles about [Ni2(((CH3)3CC6H2(S)CH2N(CH3)CH2CH2N(CH3)CH2CH2N(CH3)CH2)2)(μ-benzoato)](perchlorate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

sodium benzoate
532-32-1

sodium benzoate

lithium perchlorate trihydrate

lithium perchlorate trihydrate

[Ni<sub>2</sub>(((CH<sub>3</sub>)<sub>3</sub>CC<sub>6</sub>H<sub>2</sub>(S)CH<sub>2</sub>N(CH<sub>3</sub>)CH<sub>2</sub>CH<sub>2</sub>N(CH<sub>3</sub>)CH<sub>2</sub>CH<sub>2</sub>N(CH<sub>3</sub>)CH<sub>2</sub>)<sub>2</sub>)(μ-hypophosphito)](perchlorate)
1407190-26-4

[Ni2(((CH3)3CC6H2(S)CH2N(CH3)CH2CH2N(CH3)CH2CH2N(CH3)CH2)2)(μ-hypophosphito)](perchlorate)

[Ni<sub>2</sub>(((CH<sub>3</sub>)<sub>3</sub>CC<sub>6</sub>H<sub>2</sub>(S)CH<sub>2</sub>N(CH<sub>3</sub>)CH<sub>2</sub>CH<sub>2</sub>N(CH<sub>3</sub>)CH<sub>2</sub>CH<sub>2</sub>N(CH<sub>3</sub>)CH<sub>2</sub>)<sub>2</sub>)(μ-benzoato)](perchlorate)
698370-06-8

[Ni2(((CH3)3CC6H2(S)CH2N(CH3)CH2CH2N(CH3)CH2CH2N(CH3)CH2)2)(μ-benzoato)](perchlorate)

Guidance literature:
sodium benzoate; [Ni2(((CH3)3CC6H2(S)CH2N(CH3)CH2CH2N(CH3)CH2CH2N(CH3)CH2)2)(μ-hypophosphito)](perchlorate); In methanol; at 20 ℃; for 24h; Inert atmosphere; Schlenk technique;
lithium perchlorate trihydrate; In methanol; at 20 ℃; Inert atmosphere; Schlenk technique;
DOI:10.1021/ic301710b

Reference yield: 83.0%

lithium perchlorate trihydrate

lithium perchlorate trihydrate

[Ni<sub>2</sub>(((CH<sub>3</sub>)<sub>3</sub>CC<sub>6</sub>H<sub>2</sub>(S)CH<sub>2</sub>N(CH<sub>3</sub>)CH<sub>2</sub>CH<sub>2</sub>N(CH<sub>3</sub>)CH<sub>2</sub>CH<sub>2</sub>N(CH<sub>3</sub>)CH<sub>2</sub>)<sub>2</sub>)(μ-benzoato)](perchlorate)
698370-06-8

[Ni2(((CH3)3CC6H2(S)CH2N(CH3)CH2CH2N(CH3)CH2CH2N(CH3)CH2)2)(μ-benzoato)](perchlorate)

water
7732-18-5

water

dihydrogen peroxide
7722-84-1

dihydrogen peroxide

Ni<sub>2</sub>(C<sub>38</sub>H<sub>64</sub>N<sub>6</sub>O<sub>6</sub>S<sub>2</sub>)(C<sub>6</sub>H<sub>5</sub>COO)<sup>(1+)</sup>*ClO<sub>4</sub><sup>(1-)</sup>*4H<sub>2</sub>O=(Ni<sub>2</sub>(C<sub>38</sub>H<sub>64</sub>N<sub>6</sub>O<sub>6</sub>S<sub>2</sub>)(C<sub>6</sub>H<sub>5</sub>COO))(ClO<sub>4</sub>)*4H<sub>2</sub>O

Ni2(C38H64N6O6S2)(C6H5COO)(1+)*ClO4(1-)*4H2O=(Ni2(C38H64N6O6S2)(C6H5COO))(ClO4)*4H2O

Guidance literature:
In methanol; ethanol; water; to Ni-compd. in CH3OH 35% H2O2 in H2O added, reflux for 6 h, cooled to room temp., Li-compd. in EtOH added; evaporated, filtered, elem. anal.;
DOI:10.1002/ejic.201101402

Reference yield: 72.0%

[Ni<sub>2</sub>(((CH<sub>3</sub>)<sub>3</sub>CC<sub>6</sub>H<sub>2</sub>(S)CH<sub>2</sub>N(CH<sub>3</sub>)CH<sub>2</sub>CH<sub>2</sub>N(CH<sub>3</sub>)CH<sub>2</sub>CH<sub>2</sub>N(CH<sub>3</sub>)CH<sub>2</sub>)<sub>2</sub>)(μ-benzoato)](perchlorate)
698370-06-8

[Ni2(((CH3)3CC6H2(S)CH2N(CH3)CH2CH2N(CH3)CH2CH2N(CH3)CH2)2)(μ-benzoato)](perchlorate)

C<sub>45</sub>H<sub>69</sub>N<sub>6</sub>Ni<sub>2</sub>O<sub>4</sub>S<sub>2</sub><sup>(1+)</sup>*ClO<sub>4</sub><sup>(1-)</sup>

C45H69N6Ni2O4S2(1+)*ClO4(1-)

Guidance literature:
In 1,4-dioxane; methanol; acetonitrile; at 20 ℃; for 72h;
DOI:10.1021/acs.inorgchem.1c01854
upstream raw materials:

sodium benzoate

[Ni2(((CH3)3CC6H2(S)CH2N(CH3)CH2CH2N(CH3)CH2CH2N(CH3)CH2)2)(μ-hypophosphito)](perchlorate)

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