Fe(tetraphenylporphyrinate)C₆H₅

Base Information

• Chemical Name: Fe(tetraphenylporphyrinate)C₆H₅
• CAS No.: 70936-44-6
• Molecular Formula: C₅₀H₃₃FeN₄
• Molecular Weight: 745.686
• Mol file: 70936-44-6.mol

Synonyms:Fe(tetraphenylporphyrinate)C₆H₅

Chemical Property of Fe(tetraphenylporphyrinate)C₆H₅

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Fe(tetraphenylporphyrinate)C₆H₅

There total 4 articles about Fe(tetraphenylporphyrinate)C₆H₅ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

meso-tetraphenylporphyrin iron(III) chloride (16456-81-8,170645-84-8) + phenylhydrazine (100-63-0) → Fe(tetraphenylporphyrinate)C6H5 (70936-44-6)

Guidance literature:

With oxygen; In dichloromethane; limited amounts of O2; VIS, NMR;

DOI:10.1021/ja00343a070

Reference yield: 53.0%

meso-tetraphenylporphyrin iron(III) chloride (16456-81-8,170645-84-8) → Fe(tetraphenylporphyrinate)C6H5 (70936-44-6)

Guidance literature:

With phenylmagnesium bromide; In tetrahydrofuran; diethyl ether; PhMgBr (3 M ether soln.) added under Ar to stirred soln. of Fe complex in dry O2-free THF, 2,6-di-tert-butyl-4-methylphenol (BHT) added after 10 min; solvent evapd. in vac., chromd. (basic alumina, THF/hexane contg. 0.025% BHT), evapd., triturated with hexane, filtered, dried in vac.;

DOI:10.1021/ja00376a069

Reference yield:

Fe(C20H8N3(C6H5)4N(C6H5))Cl (83219-61-8) → Fe(tetraphenylporphyrinate)C6H5 (70936-44-6)

Guidance literature:

With sodium dithionite; In water; toluene; Fe-complex was treated with Na2S2O4 in toluene-H2O mixt. for 1 d;

DOI:10.1021/ja00386a074

upstream raw materials:

meso-tetraphenylporphyrin iron(III) chloride

phenylhydrazine

(tetraphenylporphyrine)Fe(III)CH₂C₆H₅

Fe(C₂₀H₈N₃(C₆H₅)4N(C₆H₅))Cl

Downstream raw materials:

{(C₂₀H₈(C₆H₅)4N₄)Fe(C₆H₅)(NO)}

Fe(C₂₀H₈N₃(C₆H₅)4N(C₆H₅))Cl

5,10,15,20-tetraphenyl porphyrin iron

meso-tetraphenylporphyrin iron(III) chloride

Refernces

• 1、 Cocolios, P.,Lagrange, G.,Guilard, R.. "SYNTHESE ET CARACTERISATION PAR RMN 1H D'ALKYL(ARYL)FERRIPORPHYRINES A LIAISON ? METAL-CARBONE". . p. 65 - 80. Retrieved 2007/10/02.