Phosphoric acid dibenzyl ester (1R,2S,3R,4R,5S,6R)-2,5-bis-benzyloxy-6-(bis-benzyloxy-phosphoryloxy)-3-hydroxy-4-triethylsilanyloxy-cyclohexyl ester

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Chemical Name:Phosphoric acid dibenzyl ester (1R,2S,3R,4R,5S,6R)-2,5-bis-benzyloxy-6-(bis-benzyloxy-phosphoryloxy)-3-hydroxy-4-triethylsilanyloxy-cyclohexyl ester
CAS No.:141725-53-3
Molecular Formula:C₅₄H₆₄O₁₂P₂Si
Molecular Weight:995.128
Hs Code.:

Phosphoric acid dibenzyl ester (1R,2S,3R,4R,5S,6R)-2,5-bis-benzyloxy-6-(bis-benzyloxy-phosphoryloxy)-3-hydroxy-4-triethylsilanyloxy-cyclohexyl ester

Synonyms:Phosphoric acid dibenzyl ester (1R,2S,3R,4R,5S,6R)-2,5-bis-benzyloxy-6-(bis-benzyloxy-phosphoryloxy)-3-hydroxy-4-triethylsilanyloxy-cyclohexyl ester

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Chemical Property of Phosphoric acid dibenzyl ester (1R,2S,3R,4R,5S,6R)-2,5-bis-benzyloxy-6-(bis-benzyloxy-phosphoryloxy)-3-hydroxy-4-triethylsilanyloxy-cyclohexyl ester

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Technology Process of Phosphoric acid dibenzyl ester (1R,2S,3R,4R,5S,6R)-2,5-bis-benzyloxy-6-(bis-benzyloxy-phosphoryloxy)-3-hydroxy-4-triethylsilanyloxy-cyclohexyl ester

There total 9 articles about Phosphoric acid dibenzyl ester (1R,2S,3R,4R,5S,6R)-2,5-bis-benzyloxy-6-(bis-benzyloxy-phosphoryloxy)-3-hydroxy-4-triethylsilanyloxy-cyclohexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 994-30-9
triethylsilyl chloride

: 114419-02-2
(+)-3,6-di-O-benzyl-4,5-bis-O-(di-O-benzylphospho)-myo-inositol

: 141725-53-3
Phosphoric acid dibenzyl ester (1R,2S,3R,4R,5S,6R)-2,5-bis-benzyloxy-6-(bis-benzyloxy-phosphoryloxy)-3-hydroxy-4-triethylsilanyloxy-cyclohexyl ester

Guidance literature:: With pyridine;
DOI:10.1016/S0040-4039(00)80731-5

Reference yield: 78.0%

: 120065-89-6,128051-59-2
Phosphoric acid dibenzyl ester (1R,2R,4S,5S,6R)-2,5-bis-benzyloxy-6-(bis-benzyloxy-phosphoryloxy)-3-oxo-4-triethylsilanyloxy-cyclohexyl ester

: 141725-53-3
Phosphoric acid dibenzyl ester (1R,2S,3R,4R,5S,6R)-2,5-bis-benzyloxy-6-(bis-benzyloxy-phosphoryloxy)-3-hydroxy-4-triethylsilanyloxy-cyclohexyl ester

Guidance literature:: With lithium borohydride; In tetrahydrofuran; at -78 ℃; Product distribution;
DOI:10.1016/S0040-4039(00)80731-5

Reference yield:

: 990-91-0
dibenzyl [[bis(benzyloxy)phosphoryl]oxy]phosphonate

: 141725-53-3
Phosphoric acid dibenzyl ester (1R,2S,3R,4R,5S,6R)-2,5-bis-benzyloxy-6-(bis-benzyloxy-phosphoryloxy)-3-hydroxy-4-triethylsilanyloxy-cyclohexyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 1) butyl lithium / 1) THF, hexane, - 78 deg C, 5 min, 2) THF, 0 deg C, 1.5 h

2: trifluoroacetic acid / methanol / 2 h / Ambient temperature

3: pyridine / Ambient temperature

With pyridine; n-butyllithium; trifluoroacetic acid; In methanol;
DOI:10.1016/0008-6215(92)85048-5