PENTAAMMINECHLOROCOBALT(III) CHLORIDE

Base Information

• Chemical Name: PENTAAMMINECHLOROCOBALT(III) CHLORIDE
• CAS No.: 13859-51-3
• Molecular Formula: ClCo H15 N5 . 2 Cl
• Molecular Weight: 250.505
• Mol file: 13859-51-3.mol

Synonyms:Chloropentaamminecobaltdichloride (6CI);Cobalt(2+), pentaamminechloro-, dichloride (8CI);Cobalt(2+),pentaamminechloro-, dichloride, (OC-6-22)- (9CI);Chloropentaamminecobalt(III)chloride;Chloropentaamminecobalt(III) dichloride;NSC 130236;NSC 209794;NSC251010;NSC 2911;NSC 4315;Pentaaminechlorocobalt(III) chloride;Pentaamminechlorocobaltate(2+) dichloride;Pentaammine(chloro)cobalt(1+) dichloride;Pentaamminechlorocobalt(2+) dichloride;Pentaamminechlorocobalt(III) dichloride;

Chemical Property of PENTAAMMINECHLOROCOBALT(III) CHLORIDE

Chemical Property:

• Vapor Pressure: 5990mmHg at 25°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 16.20000
• Density: g/cm³
• LogP: 3.68800
• Water Solubility.: Soluble in water.

Purity/Quality:

98%,99%, ^*data from raw suppliers

Pentaamminechlorocobalt(III) chloride 98% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Uses: A nanocomposite of nanophotoadduct of pentaamminechlorocobalt(III) chloride with hexamine and polythiophene (PTh)may be used in high temperatures electrical appliances. It may be used along with potassium tris(oxalato)chromate(III) to synthesize heterometallic compound, [CoCl(NH3 )5 ] [KCr(C2 O4 )3 ]?0.5H2O.This heterometallic compound has several potential applications such as microporous hybrid material with organic π-donors.

Technology Process of PENTAAMMINECHLOROCOBALT(III) CHLORIDE

There total 51 articles about PENTAAMMINECHLOROCOBALT(III) CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

roseo chloride → pentaaminechlorocobalt(III) dichloride (13859-51-3)

Guidance literature:

With hydrogenchloride; In water; equilibrium is investigated at 70 °C;;

Reference yield:

cobalt(II) chloride hexahydrate + ammonium chloride + ammonia (7664-41-7) → pentaaminechlorocobalt(III) dichloride (13859-51-3)

Guidance literature:

With dihydrogen peroxide; In water; addn. of 30% H2O2 soln. to a mixture of powdered CoCl2*6H2O, H2O, NH3 soln. and solid NH4Cl under continous stirring; heating for 1 h on a water bath; addn. of 3n HCl soln.; heating to 60°C; filtration;; washing with 2n HCl soln.; solving in 1.2n NH3 soln. under heating at 60°C; pptn. with concd. HCl soln.; washing with 2n HCl soln., alcohol and ether; drying at 60°C;;

DOI:10.1021/ja01279a064

Reference yield:

ammonium carbonate + hydrogenchloride (7647-01-0,15364-23-5) + ammonium chloride + ammonia (7664-41-7) + cobalt(II) carbonate (759403-02-6) → pentaaminechlorocobalt(III) dichloride (13859-51-3)

Guidance literature:

With air; In water; addn. of CoCO3 in few HCl to aq. NH3 (10%) and aq. soln. of (NH4)2CO3, oxidn. with vigorous air stream, evapg. with NH4Cl, addn. of HCl, oversatg. with aq. NH3, diln. with H2O, heating with NH3 in water bath, after 1h oversatg. with HCl, heating 1h;; several extraction with aq. NH3 (2%) at heating; pptn. at heating with concd. HCl;;

upstream raw materials:

hydrogenchloride

ammonia

cobalt(II) carbonate

cobalt(II) chloride

Downstream raw materials:

cobalt(II) chloride

cobalt

hexammine cobalt(III) chloride

ammonia

Refernces

• 1、 Kong, Xiangchen,Gao, Zhonghui,Gong, Yue,Huang, Huiming,Wang, Haifeng,Liu, Porun,Yin, Huajie,Cui, Zhenduo,Li, Zhaoyang,Liang, Yanqin,Zhu, Shengli,Huang, Yunhui,Yang, Xianjin. "Enhancement of photocatalytic H2 production by metal complex electrostatic adsorption on TiO2 (B) nanosheets". . p. 3797 - 3804. Retrieved 2019.
• 2、 Hynes, W. A.,Yanowski, L. K.,Shiller, M.. "". . p. 3053 - 3054. Retrieved 1938.
• 3、 Wang, Chenlong,Zhan, Hongju,Lu, Xinhuan,Jing, Run,Zhang, Haifu,Yang, Lu,Li, Xixi,Yue, Fanfan,Zhou, Dan,Xia, Qinghua. "A recyclable cobalt(iii)-ammonia complex catalyst for catalytic epoxidation of olefins with air as the oxidant". . p. 2147 - 2156. Retrieved 2021/02/06.