1-[3,5-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-β-D-arabinofuranosyl]-3-(2,4-dinitrophenylsulfenyl)uracil

Base Information

Chemical Name:1-[3,5-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-β-D-arabinofuranosyl]-3-(2,4-dinitrophenylsulfenyl)uracil
CAS No.:786703-39-7
Molecular Formula:C₂₇H₄₀N₄O₁₁SSi₂
Molecular Weight:684.872
Hs Code.:

Synonyms:1-[3,5-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-β-D-arabinofuranosyl]-3-(2,4-dinitrophenylsulfenyl)uracil

Suppliers and Price of 1-[3,5-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-β-D-arabinofuranosyl]-3-(2,4-dinitrophenylsulfenyl)uracil

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-[3,5-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-β-D-arabinofuranosyl]-3-(2,4-dinitrophenylsulfenyl)uracil

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-[3,5-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-β-D-arabinofuranosyl]-3-(2,4-dinitrophenylsulfenyl)uracil

There total 1 articles about 1-[3,5-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-β-D-arabinofuranosyl]-3-(2,4-dinitrophenylsulfenyl)uracil which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 528-76-7
2,4-dinitrobenzenesulfenyl chloride

: 104477-70-5
5',3'-O-(tetraisopropyldisiloxane-1,3-di-yl)-1-β-D-arabinofuranosyl-uracil

: 786703-39-7
1-[3,5-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-β-D-arabinofuranosyl]-3-(2,4-dinitrophenylsulfenyl)uracil

Guidance literature:: 5',3'-O-(tetraisopropyldisiloxane-1,3-di-yl)-1-β-D-arabinofuranosyl-uracil; With pyridine; chloro-trimethyl-silane; for 0.166667h;

2,4-dinitrobenzenesulfenyl chloride; With pyridine; for 3h;

With ammonium hydroxide; In pyridine; for 0.5h; Further stages.;
DOI:10.1016/j.tetlet.2004.08.006

Reference yield: 81.0%

: 106-95-6
allyl bromide

: 786703-39-7
1-[3,5-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-β-D-arabinofuranosyl]-3-(2,4-dinitrophenylsulfenyl)uracil

: 786703-33-1
1-[3,5-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-2-O-allyl-β-D-arabinofuranosyl]-3-(2,4-dinitrophenylsulfenyl)uracil

Guidance literature:: With 2-tert-butylimino-2-diethylamino-1,3-dimethyl-perhydro-1,3,2-diazaphosphorine; In acetonitrile; at 20 ℃; for 2h;
DOI:10.1007/s11172-005-0243-2

Reference yield:

: 786703-39-7
1-[3,5-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-β-D-arabinofuranosyl]-3-(2,4-dinitrophenylsulfenyl)uracil

: 786703-40-0
1-[3,5-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-2-O-(2,3-dihydroxypropyl)-β-D-arabinofuranosyl]-3-(2,4-dinitrophenylsulfenyl)uracil

Guidance literature:: Multi-step reaction with 2 steps

1: 81 percent / 2-tBu-imino-2-Et₂N-1,3-di-Me-perhydro-1,3,2-diazaphosphorine / acetonitrile / 2 h / 20 °C

2: 90 percent / N-methylmorpholine N-oxide; osmium tetroxide / acetone; H₂O / 72 h / 20 °C

With osmium(VIII) oxide; 4-methylmorpholine N-oxide; 2-tert-butylimino-2-diethylamino-1,3-dimethyl-perhydro-1,3,2-diazaphosphorine; In water; acetone; acetonitrile;
DOI:10.1007/s11172-005-0243-2