1-p-tolyl-2,3,4-tri-O-benzyl-7-methyl-1-thio-β-D-glucoheptopyrano-6-ulose

Base Information

Chemical Name:1-p-tolyl-2,3,4-tri-O-benzyl-7-methyl-1-thio-β-D-glucoheptopyrano-6-ulose
CAS No.:1400907-04-1
Molecular Formula:C₃₆H₃₈O₆S
Molecular Weight:598.76
Hs Code.:

Synonyms:1-p-tolyl-2,3,4-tri-O-benzyl-7-methyl-1-thio-β-D-glucoheptopyrano-6-ulose

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-p-tolyl-2,3,4-tri-O-benzyl-7-methyl-1-thio-β-D-glucoheptopyrano-6-ulose

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Technology Process of 1-p-tolyl-2,3,4-tri-O-benzyl-7-methyl-1-thio-β-D-glucoheptopyrano-6-ulose

There total 2 articles about 1-p-tolyl-2,3,4-tri-O-benzyl-7-methyl-1-thio-β-D-glucoheptopyrano-6-ulose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 67-56-1
methanol

: 1400906-85-5
1-p-tolyl-2,3,4-tri-O-benzyl-7-deoxy-7-diazo-1-thio-β-D-glucoheptopyran-6-ulose

: 1400907-04-1
1-p-tolyl-2,3,4-tri-O-benzyl-7-methyl-1-thio-β-D-glucoheptopyrano-6-ulose

Guidance literature:: With copper acetylacetonate; In methanol; at 100 ℃; for 0.0833333h; Microwave irradiation;
DOI:10.1021/jo300986c

Reference yield:

: 479252-05-6
((2R,3R,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-p-tolylsulfanyl-tetrahydro-pyran-2-yl)-methanol

: 1400907-04-1
1-p-tolyl-2,3,4-tri-O-benzyl-7-methyl-1-thio-β-D-glucoheptopyrano-6-ulose

Guidance literature:: Multi-step reaction with 4 steps

1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane; water / 2 h / 20 °C

2: oxalyl dichloride; 2,6-dimethylpyridine / toluene / 0 - 20 °C

3: toluene; diethyl ether / 1 h / -20 °C

4: copper acetylacetonate / methanol / 0.08 h / 100 °C / Microwave irradiation

With 2,6-dimethylpyridine; copper acetylacetonate; oxalyl dichloride; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; In methanol; diethyl ether; dichloromethane; water; toluene;
DOI:10.1021/jo300986c