2-nitrophenyl vinyl sulfoxide

Base Information

• Chemical Name: 2-nitrophenyl vinyl sulfoxide
• CAS No.: 72622-66-3
• Molecular Formula: C₈H₇NO₃S
• Molecular Weight: 197.214
• Mol file: 72622-66-3.mol

Synonyms:2-nitrophenyl vinyl sulfoxide

Chemical Property of 2-nitrophenyl vinyl sulfoxide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 2-nitrophenyl vinyl sulfoxide

There total 3 articles about 2-nitrophenyl vinyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

2-nitrophenyl vinyl sulfide (54848-82-7) → 2-nitrophenyl vinyl sulfoxide (72622-66-3)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 1h;

DOI:10.1021/jo01294a026

Reference yield:

2-chloro-1-(trimethylsilyl)ethyl 2-nitrophenyl sulfide (72610-20-9) → 2-nitrophenyl vinyl sulfoxide (72622-66-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 98.6 percent / aq. ethanol / 48 h / 50 °C

2: 82 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 1 h / 20 °C

With 3-chloro-benzenecarboperoxoic acid; In ethanol; dichloromethane;

DOI:10.1021/jo01294a026

Reference yield:

2-nitrobenzenesulfenyl chloride (7669-54-7) → 2-nitrophenyl vinyl sulfoxide (72622-66-3)

Guidance literature:

Multi-step reaction with 3 steps

1: 94 percent / CH₂Cl₂ / 1. -76 deg C; 2. 20 deg C, 20 h

2: 98.6 percent / aq. ethanol / 48 h / 50 °C

3: 82 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 1 h / 20 °C

With 3-chloro-benzenecarboperoxoic acid; In ethanol; dichloromethane;

DOI:10.1021/jo01294a026

upstream raw materials:

2-nitrophenyl vinyl sulfide

2-chloro-1-(trimethylsilyl)ethyl 2-nitrophenyl sulfide

2-nitrobenzenesulfenyl chloride

Refernces