[[(CHC₅H₂N(C₆H₄(OC₂H₄)2OCH₂))2]Cu(2,9-bis-(p-formylphenyl)-1,10-phenanthroline)](PF₆)

Base Information

• Chemical Name: [[(CHC₅H₂N(C₆H₄(OC₂H₄)2OCH₂))2]Cu(2,9-bis-(p-formylphenyl)-1,10-phenanthroline)](PF₆)
• CAS No.: 165814-91-5
• Molecular Formula: C₆₀H₅₀CuN₄O₈*F₆P
• Molecular Weight: 1163.59
• Mol file: 165814-91-5.mol

Synonyms:[[(CHC₅H₂N(C₆H₄(OC₂H₄)2OCH₂))2]Cu(2,9-bis-(p-formylphenyl)-1,10-phenanthroline)](PF₆)

Chemical Property of [[(CHC₅H₂N(C₆H₄(OC₂H₄)2OCH₂))2]Cu(2,9-bis-(p-formylphenyl)-1,10-phenanthroline)](PF₆)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [[(CHC₅H₂N(C₆H₄(OC₂H₄)2OCH₂))2]Cu(2,9-bis-(p-formylphenyl)-1,10-phenanthroline)](PF₆)

There total 1 articles about [[(CHC₅H₂N(C₆H₄(OC₂H₄)2OCH₂))2]Cu(2,9-bis-(p-formylphenyl)-1,10-phenanthroline)](PF₆) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

tetrakis(acetonitrile)copper(I)tetrafluoroborate + ((C2H4O)2C6H4)NC5H2C2H2C5H2N(C6H4(C2H4O)2)OC2H4O (90030-13-0) + 2,9‐bis(4-formylphenyl)‐1,10‐phenanthroline (120085-99-6) → [[(CHC5H2N(C6H4(OC2H4)2OCH2))2]Cu(2,9-bis-(p-formylphenyl)-1,10-phenanthroline)](PF6) (165814-91-5)

Guidance literature:

With KPF₆; In dichloromethane; under Ar; a soln. of Cu complex in CH3CN was added to a soln. of the macrocycle in CH2Cl2, after stirring for 20 min 2,9-bis(p-formylphenyl)-1,10-phenanthroline was added, the mixt. was stirred for 2 h; satd. soln. of KPF6 in H2O was added, the org. layer was extd. and evapd. to dryness;

DOI:10.1021/ja0119907

Reference yield:

[[(CHC5H2N(C6H4(OC2H4)2OCH2))2]Cu(2,9-bis-(p-formylphenyl)-1,10-phenanthroline)](PF6) (165814-91-5) + 3,5-Di-tert-butylbenzaldehyde (17610-00-3) + bis(3-hexyl-4-methyl-2-pyrrolyl)methane (126136-05-8) → [(C6H3NC6H4(OC2H4)2OCH2)2]*Cu(1+)*[(C6H4(C62H89N4)NC6H3)2]*PF6(1-)=[C34H34N2O6]Cu[C148H192N10](PF6)

Guidance literature:

With trifluoroacetic acid; chloranil (tetrachloro-p-benzoquinone); KPF₆; In dichloromethane; under Ar; to a soln. of the complex, the aldehyde and the (dipyrryl)methane in CH2Cl2 was added CF3CO2H, the mixt. was stirred for 16h at 25°C, the chloranil (tetrachloro-p-benzoquinone) was added, the mixt. was refluxed for 1.5 h; NaHCO3 was added, the org. layer was washed with H2O, a satd. soln. of KPF6 in H2O was added, the soln. was evapd., the residue was chromd. on SiO2 (CH2Cl2/MeOH) and then alumina (CH2Cl2);

DOI:10.1021/ja0119907

upstream raw materials:

((C₂H₄O)2C₆H₄)NC₅H₂C₂H₂C₅H₂N(C₆H₄(C₂H₄O)2)OC₂H₄O

2,9‐bis(4-formylphenyl)‐1,10‐phenanthroline