methyl cis-9,10-epoxyoctadecanoate

Base Information

• Chemical Name: methyl cis-9,10-epoxyoctadecanoate
• CAS No.: 38003-69-9
• Molecular Formula: C₁₉H₃₆O₃
• Molecular Weight: 312.493

Synonyms:methyl cis-9,10-epoxyoctadecanoate

Chemical Property of methyl cis-9,10-epoxyoctadecanoate

Chemical Property:

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Technology Process of methyl cis-9,10-epoxyoctadecanoate

There total 19 articles about methyl cis-9,10-epoxyoctadecanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.8%

Methyl oleate (112-62-9) → (Z)-9,10-epoxyoctadecanoic acid methyl ester (2500-59-6,2566-91-8,6084-76-0,38003-69-9,38003-75-7,38003-77-9,79854-41-4,112244-28-7)

Guidance literature:

With formic acid; dihydrogen peroxide; In water; at 0 - 23 ℃; for 24h;

DOI:10.1007/s11746-009-1441-0

Reference yield: 96.0%

methyl (9E)-octadec-9-enoate (2462-84-2) → (E)-9,10-epoxyoctadecanoic acid methyl ester (2500-59-6,2566-91-8,6084-76-0,38003-69-9,38003-75-7,38003-77-9,79854-41-4,112244-28-7)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 21h;

DOI:10.1039/b202891c

Reference yield: 12.0%

methanol (67-56-1) + cis-9,10-epoxystearic acid (24560-98-3) → (Z)-9,10-epoxyoctadecanoic acid methyl ester (2500-59-6,2566-91-8,6084-76-0,38003-69-9,38003-75-7,38003-77-9,79854-41-4,112244-28-7)

Guidance literature:

With trifluoroacetic anhydride; In benzene; at 25 ℃; for 0.666667h;

upstream raw materials:

octadec-9-enoic acid methyl ester

methanol

trans-9,10-epoxystearic acid

methyl (9E)-octadec-9-enoate

Downstream raw materials:

trans-9,10-epoxystearic acid

methyl (9E)-octadec-9-enoate

(9S,10R)-10-Hydroxy-9-phenylselanyl-octadecanoic acid methyl ester

(9R,10S)-9-Hydroxy-10-phenylselanyl-octadecanoic acid methyl ester

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