pentamethylcyclopentadienyliridium(III) PMe₃ dihydride

Base Information

• Chemical Name: pentamethylcyclopentadienyliridium(III) PMe₃ dihydride
• CAS No.: 80146-01-6
• Molecular Formula: C₁₃H₂₆IrP
• Molecular Weight: 405.543
• Mol file: 80146-01-6.mol

Synonyms:pentamethylcyclopentadienyliridium(III) PMe₃ dihydride

Chemical Property of pentamethylcyclopentadienyliridium(III) PMe₃ dihydride

Chemical Property:

Purity/Quality:

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Technology Process of pentamethylcyclopentadienyliridium(III) PMe₃ dihydride

There total 3 articles about pentamethylcyclopentadienyliridium(III) PMe₃ dihydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(pentamethylcyclopentadienyl)(PMe3)iridium hydrido chloride + cyclohexane (110-82-7,25012-93-5) → pentamethylcyclopentadienyliridium(III) PMe3 dihydride (80146-01-6) + (η5-Me5C5)(PMe3)Ir(C6H11)(H)

Guidance literature:

With tert.-butyl lithium; In neat (no solvent); byproducts: LiCl; (N2 or vac.); solid mixt. of Ir complex and t-BuLi dissolved in hydrocarbon, stirred at ambient temp. for 3-12 h; filtered (Celite), concd. (vac.), dissolved in C6D6; not isolated, detected by NMR;

DOI:10.1021/ja0024993

Reference yield:

(pentamethylcyclopentadienyl)(PMe3)iridium hydrido chloride + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → pentamethylcyclopentadienyliridium(III) PMe3 dihydride (80146-01-6) + (η(5)-C5Me5)(PMe3)Ir(C6H5)(H)

Guidance literature:

With tert.-butyl lithium; In neat (no solvent); byproducts: LiCl; (N2 or vac.); solid mixt. of Ir complex and t-BuLi dissolved in hydrocarbon, stirred at ambient temp. for 3-12 h; filtered (Celite), concd. (vac.), dissolved in C6D6; not isolated, detected by NMR;

DOI:10.1021/ja0024993

Reference yield:

(η5-Me5C5)(PMe3)Ir(C6H11)(H) + bis(pentafluorophenyl)borohydride (165612-94-2) → pentamethylcyclopentadienyliridium(III) PMe3 dihydride (80146-01-6) + bis(pentafluorophenyl)borylcyclohexane (245043-30-5)

Guidance literature:

In benzene-d6; room temp.;

DOI:10.1021/ja991258w

upstream raw materials:

bis(pentafluorophenyl)borohydride

cyclohexane

benzene

Downstream raw materials:

(η(5)-C5Me5)(PMe3)Ir(BPh2)(H)

(C₅Me₅)(PMe₃)Ir(m-C₆H₄CH₃)(H)

(C₅Me₅)(PMe₃)Ir(o-C₆H₄CH₃)(H)

(C₅Me₅)(PMe₃)Ir(p-C₆H₄CH₃)(H)