C₃₂H₃₂N₆O₉

Base Information

• Chemical Name: C₃₂H₃₂N₆O₉
• CAS No.: 1363597-61-8
• Molecular Formula: C₃₂H₃₂N₆O₉
• Molecular Weight: 644.641
• Mol file: 1363597-61-8.mol

Synonyms:C₃₂H₃₂N₆O₉

Chemical Property of C₃₂H₃₂N₆O₉

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₂H₃₂N₆O₉

There total 5 articles about C₃₂H₃₂N₆O₉ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

tetraethyl (4'-(p-aminophenoxy)methylene-2,2':6',2''-terpyridine-6,6''-diyl)bis(methylenenitrilo)tetrakis(acetate) (1363597-60-7) → C32H32N6O9 (1363597-61-8)

Guidance literature:

With water; potassium hydroxide; In ethanol; at 20 ℃; for 20h;

DOI:10.1021/ic202195a

Reference yield:

4'-hydroxymethyl-6-6''-bis(bromomethyl)-2,2':6',2''-terpyridine (1363597-57-2) → C32H32N6O9 (1363597-61-8)

Guidance literature:

Multi-step reaction with 4 steps

1.1: sodium hydride / acetonitrile / 1 h / Inert atmosphere

1.2: Inert atmosphere

2.1: phosphorus tribromide / tetrahydrofuran / 2 h / 20 °C

3.1: sodium hydride / acetonitrile / 0.25 h / 20 °C / Inert atmosphere

3.2: Inert atmosphere

4.1: water; potassium hydroxide / ethanol / 20 h / 20 °C

With water; phosphorus tribromide; sodium hydride; potassium hydroxide; In tetrahydrofuran; ethanol; acetonitrile;

DOI:10.1021/ic202195a

Reference yield:

tetraethyl (4'-hydroxymethyl-2,2':6',2''-terpyridine-6,6''-diyl)bis(methylenenitrilo)tetrakis(acetate) (1363597-58-3) → C32H32N6O9 (1363597-61-8)

Guidance literature:

Multi-step reaction with 3 steps

1.1: phosphorus tribromide / tetrahydrofuran / 2 h / 20 °C

2.1: sodium hydride / acetonitrile / 0.25 h / 20 °C / Inert atmosphere

2.2: Inert atmosphere

3.1: water; potassium hydroxide / ethanol / 20 h / 20 °C

With water; phosphorus tribromide; sodium hydride; potassium hydroxide; In tetrahydrofuran; ethanol; acetonitrile;

DOI:10.1021/ic202195a

upstream raw materials:

4'-hydroxymethyl-6-6''-bis(bromomethyl)-2,2':6',2''-terpyridine

tetraethyl (4'-hydroxymethyl-2,2':6',2''-terpyridine-6,6''-diyl)bis(methylenenitrilo)tetrakis(acetate)

tetraethyl (4′-bromomethyl-2,2′:6′,2′-terpyridine-6,6′-diyl)bis(methylenenitrilo)tetrakis(acetate)

4-amino-phenol