Pt(2,2'-biphenyl)(PPh₃)2

Base Information

Chemical Name:Pt(2,2'-biphenyl)(PPh₃)2
CAS No.:75731-11-2
Molecular Formula:C₄₈H₃₈P₂Pt
Molecular Weight:871.857
Hs Code.:

Synonyms:Pt(2,2'-biphenyl)(PPh₃)2

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Chemical Property of Pt(2,2'-biphenyl)(PPh₃)2

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Technology Process of Pt(2,2'-biphenyl)(PPh₃)2

There total 3 articles about Pt(2,2'-biphenyl)(PPh₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: Pt(2,2'-biphenyl)(1,5-cyclooctadiene)

: 75731-11-2
Pt(2,2'-biphenyl)(PPh₃)2

Guidance literature:: With PPh₃; In dichloromethane; to a soln. of Pt-complex in CH2Cl2 PPh3 was added, stirred overnight atroom temp.; evapd. to dryness, washed with Et2O, filtered, n-hexane was added to the filtrate, concd.; elem. anal.;
DOI:10.1016/S0022-328X(00)84669-0

Reference yield: 73.0%

: 10199-34-5,14056-88-3,15604-36-1
bis(triphenylphosphine)platinum(II) dichloride

: 2,2'-dilithiobiphenyl

: 75731-11-2
Pt(2,2'-biphenyl)(PPh₃)2

Guidance literature:: In diethyl ether; hexane; under N2; a soln. of 2,2'-dilithiobiphenyl in hexanes was added dropwiseto a soln. of Pt complex in (CH3CH2)2O, the mixt. was allowed to react for a few h; H2O was added, the org. layer was dried with MgSO4, evapd.; elem. anal.;
DOI:10.1021/om010111m

Reference yield: 72.0%

: 12120-15-9
ethylenebis(triphenylphosphine)platinum⁽⁰⁾

: 108-90-7
chlorobenzene

: 75731-11-2
Pt(2,2'-biphenyl)(PPh₃)2

Guidance literature:: With lithium 2,2,6,6-tetramethylpiperidide; n-BuLi; In tetrahydrofuran; hexane; (inert atmosphere); addn. of chlorobenzene and the Pt complex in THF to lithium 2,2,6,6-teramethylpiperidide in THF at -60°C, stirring (0°C, 2.5 h, room temp., 2 h), addn. of n-BuLi in hexane, stirring (room temp., 16 h); evapn., addn. of Et2O, filtration (SiO2), solvent removal; elem anal.;