C₁₄H₁₆

Base Information

• Chemical Name: C₁₄H₁₆
• CAS No.: 795307-39-0
• Molecular Formula: C₁₄H₁₆
• Molecular Weight: 184.281
• Mol file: 795307-39-0.mol

Synonyms:C₁₄H₁₆

Chemical Property of C₁₄H₁₆

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of C₁₄H₁₆

There total 1 articles about C₁₄H₁₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-benzylhept-2-yn-1-amine (1379038-80-8) → oct-1-en-3-yn-2-ylbenzene (886433-28-9) + C14H16 (795307-39-0) + 2-butyl-4-phenyl-1-buten-3-yne

Guidance literature:

Multi-step reaction with 2 steps

1: Lu(N(SiMe₃)2)3 / toluene / 48 h / 100 °C / Inert atmosphere; Glovebox; Schlenk technique; Sealed tube

2: Lu(N(SiMe₃)2)3 / toluene / 12 h / 130 °C / Inert atmosphere; Glovebox; Schlenk technique; Sealed tube

With Lu(N(SiMe₃)2)3; In toluene;

DOI:10.1002/anie.201605822

Reference yield: 39.0%

2,3-dimethyl-2,3-butane diol (76-09-5) + C14H16 (795307-39-0) + C17H17BO4 → C31H41BO4

Guidance literature:

C₁₄H₁₆; With bis[(trimethylsilyl)methyl](1,5-cyclooctadiene)palladium(II); C₂₈H₃₇BNP; In toluene; at 20 ℃; for 0.25h; Glovebox;

C₁₇H₁₇BO₄; In toluene; at 50 ℃; for 12h; Glovebox;

2,3-dimethyl-2,3-butane diol; With triethylamine; In dichloromethane; at 20 ℃; for 1h; diastereoselective reaction; Glovebox;

DOI:10.1002/anie.202108534

Reference yield:

dimethylmonochlorosilane (1066-35-9) + C14H16 (795307-39-0) → C16H24Si

Guidance literature:

With bis(acetylacetonato)palladium(II); diisobutylaluminium hydride; triethylphosphine; In toluene; at 80 ℃; for 12h; diastereoselective reaction; Inert atmosphere; Glovebox;

DOI:10.1021/ol4001334

upstream raw materials:

N-benzylhept-2-yn-1-amine