3-(4-methoxy-benzyloxy)-pent-4-enoic acid 4-(4-methoxy-benzyloxy)-1-methyl-hex-5-enyl ester

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Chemical Name:3-(4-methoxy-benzyloxy)-pent-4-enoic acid 4-(4-methoxy-benzyloxy)-1-methyl-hex-5-enyl ester
CAS No.:935475-90-4
Molecular Formula:C₂₈H₃₆O₆
Molecular Weight:468.59
Hs Code.:

Synonyms:3-(4-methoxy-benzyloxy)-pent-4-enoic acid 4-(4-methoxy-benzyloxy)-1-methyl-hex-5-enyl ester

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Chemical Property of 3-(4-methoxy-benzyloxy)-pent-4-enoic acid 4-(4-methoxy-benzyloxy)-1-methyl-hex-5-enyl ester

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Technology Process of 3-(4-methoxy-benzyloxy)-pent-4-enoic acid 4-(4-methoxy-benzyloxy)-1-methyl-hex-5-enyl ester

There total 4 articles about 3-(4-methoxy-benzyloxy)-pent-4-enoic acid 4-(4-methoxy-benzyloxy)-1-methyl-hex-5-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 935475-92-6
(3S)-3-[(4-methoxybenzyl)oxy]-4-pentenoic acid

: 935475-91-5
(2S,5R)-5-[(4-methoxybenzyl)oxy]hept-6-en-2-ol

: 935475-90-4
3-(4-methoxy-benzyloxy)-pent-4-enoic acid 4-(4-methoxy-benzyloxy)-1-methyl-hex-5-enyl ester

Guidance literature:: DOI:10.1002/hlca.200900410

Reference yield:

: (2S,5R)-2-hydroxy-5-[(4-methoxybenzyl)oxy]hept-6-en-1-yl 4-methylbenzenesulfonate

: 935475-90-4
3-(4-methoxy-benzyloxy)-pent-4-enoic acid 4-(4-methoxy-benzyloxy)-1-methyl-hex-5-enyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 88 percent / LAH / tetrahydrofuran / 0 - 20 °C

2: 89 percent / 2,4,6-trichlorobenzoyl chloride; Et₃N; DMAP / CH₂Cl₂ / 20 °C

With dmap; lithium aluminium tetrahydride; 2,4,6-trichlorobenzoyl chloride; triethylamine; In tetrahydrofuran; dichloromethane; 2: Yamaguchi esterification;
DOI:10.1016/j.tetlet.2007.02.040

Reference yield:

: 317855-28-0
(3S)-3-((methoxyphenyl)methyl)oxy-5-hydroxy-1-pentene

: 935475-90-4
3-(4-methoxy-benzyloxy)-pent-4-enoic acid 4-(4-methoxy-benzyloxy)-1-methyl-hex-5-enyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 84 percent / Dess-Martin periodinane / CH₂Cl₂ / 0 - 20 °C

2: 82 percent / NaClO₂; NaH₂PO₄; 2-methyl-2-butene / 0 - 20 °C

3: 89 percent / 2,4,6-trichlorobenzoyl chloride; Et₃N; DMAP / CH₂Cl₂ / 20 °C

With dmap; sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; 2,4,6-trichlorobenzoyl chloride; Dess-Martin periodane; triethylamine; In dichloromethane; 3: Yamaguchi esterification;
DOI:10.1016/j.tetlet.2007.02.040