317855-28-0Relevant articles and documents
Novel heteroatom-containing vitamin D3 analogs: Efficient synthesis of 1α,25-dihydroxyvitamin D3-26,23-lactam
Kato, Yuko,Hashimoto, Yuichi,Nagasawa, Kazuo
, p. 488 - 499 (2003)
Vitamin D3 and its synthetic analogs are promising compounds for controlling various types of cell differentiation. In this article, we describe the synthesis of novel vitamin D3 analogs containing heteroatoms in their side chains - so-called vitamin D3 lactam analogs - via 1,3-dipolar cycloaddition reaction as a key step.
A stereoselective total synthesis of decarestrictine I
Yadav, Jhillu Singh,Venkatesh, Miriyal,Kumar, Alleni Suman,Reddy, Poli Adi Narayana,Reddy, Basi V. Subba,Prasad, Attaluri R.
, p. 830 - 838 (2014/07/07)
A convergent and stereoselective total synthesis of decarestrictine I, a polyketide natural product, is described. Both acid and alcohol fragments were prepared from the readily available L-malic acid via Still-Gennari olefination and Sharpless asymmetric epoxidation. The Steglich esterification and ring-closing metathesis (RCM) are employed to combine both acid and alcohol fragments. Copyright
Total synthesis of nonenolide
Meshram, Harshadas Mitaram,Kumar, Dachepally Aravind,Ramesh, Palakuri
experimental part, p. 1422 - 1427 (2010/09/12)
A novel synthetic route has been reported for the synthesis of nonenolide. The syntheses of fragments were initiated from commercially available and inexpensive starting materials. The synthesis involves key steps like Sharpless epoxidation, Jacobsen's re
