methyl (3R,5E,7S)-3,7-bis{[(tert-butyl)(dimethyl)silyl]oxy}-7-phenylhept-5-enoate

Base Information

Chemical Name:methyl (3R,5E,7S)-3,7-bis{[(tert-butyl)(dimethyl)silyl]oxy}-7-phenylhept-5-enoate
CAS No.:1313835-56-1
Molecular Formula:C₂₆H₄₆O₄Si₂
Molecular Weight:478.82
Hs Code.:

Synonyms:methyl (3R,5E,7S)-3,7-bis{[(tert-butyl)(dimethyl)silyl]oxy}-7-phenylhept-5-enoate

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Chemical Property of methyl (3R,5E,7S)-3,7-bis{[(tert-butyl)(dimethyl)silyl]oxy}-7-phenylhept-5-enoate

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Technology Process of methyl (3R,5E,7S)-3,7-bis{[(tert-butyl)(dimethyl)silyl]oxy}-7-phenylhept-5-enoate

There total 9 articles about methyl (3R,5E,7S)-3,7-bis{[(tert-butyl)(dimethyl)silyl]oxy}-7-phenylhept-5-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: (tert-butyl)(dimethyl){[(1S)-1-phenylprop-2-en-1-yl]oxy}silane

: 1313835-59-4
dimethyl (3R,5E,8R)-3,8-bis{[(tert-butyl)(dimethyl)silyl]oxy}dec-5-enedioate

: 1313835-56-1
methyl (3R,5E,7S)-3,7-bis{[(tert-butyl)(dimethyl)silyl]oxy}-7-phenylhept-5-enoate

Guidance literature:: With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; at 20 ℃; for 24h; Inert atmosphere;
DOI:10.1002/hlca.201000365

Reference yield: 60.0%

: (tert-butyl)(dimethyl){[(1S)-1-phenylprop-2-en-1-yl]oxy}silane

: 121980-44-7
methyl (3R)-3-<(t-butyl)dimethylsilyloxy>hex-5-enoate

: 1313835-56-1
methyl (3R,5E,7S)-3,7-bis{[(tert-butyl)(dimethyl)silyl]oxy}-7-phenylhept-5-enoate

: 1313835-59-4
dimethyl (3R,5E,8R)-3,8-bis{[(tert-butyl)(dimethyl)silyl]oxy}dec-5-enedioate

Guidance literature:: With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; at 20 ℃; for 24h; Inert atmosphere;
DOI:10.1002/hlca.201000365

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1313835-56-1
methyl (3R,5E,7S)-3,7-bis{[(tert-butyl)(dimethyl)silyl]oxy}-7-phenylhept-5-enoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: 1H-imidazole / dichloromethane / 0.08 h / 0 °C

1.2: 0.5 h / 20 °C

2.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 24 h / 20 °C / Inert atmosphere

With 1H-imidazole; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane;
DOI:10.1002/hlca.201000365