TRI-P-TOLYLCHLOROTIN

Base Information

• Chemical Name: TRI-P-TOLYLCHLOROTIN
• CAS No.: 32538-28-6
• Molecular Formula: C21H21 Cl Sn
• Molecular Weight: 427.561
• Hs Code.: 2931900090
• Mol file: 32538-28-6.mol

Synonyms:Stannane,chlorotri-p-tolyl- (8CI); Chlorotri-p-tolylstannane; Chlorotri-p-tolyltin;Chlorotris(4-methylphenyl)stannane; Chlorotris(p-methylphenyl)stannane;Chlorotris(p-tolyl)tin; Tri-p-tolyltin chloride; Tris(p-tolyl)tin chloride

Chemical Property of TRI-P-TOLYLCHLOROTIN

Chemical Property:

• Vapor Pressure: 1.23E-07mmHg at 25°C
• Melting Point: 108°C
• Boiling Point: 443.2°C at 760 mmHg
• Flash Point: 221.8°C
• PSA: 0.00000
• LogP: 3.81750

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRI-P-TOLYLCHLOROTIN

There total 7 articles about TRI-P-TOLYLCHLOROTIN which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tin(IV) chloride (7646-78-8) + tetra(p-tolyl)tin (6746-22-1) → tris(4-methylphenyl)tin(IV) chloride (32538-28-6)

Guidance literature:

In neat (no solvent); heating; elem. anal.;

DOI:10.1016/S0020-1693(00)87420-4

Reference yield:

para-bromotoluene (106-38-7) → tris(4-methylphenyl)tin(IV) chloride (32538-28-6)

Guidance literature:

Multi-step reaction with 2 steps

1: Li; Sn-Hg alloy / diethyl ether

With Li; Sn-Hg alloy; In diethyl ether;

Reference yield:

4-methylphenylmercuric chloride (539-43-5) → tris(4-methylphenyl)tin(IV) chloride (32538-28-6)

Guidance literature:

Multi-step reaction with 2 steps

1: Na-Sn alloy / xylene

With Na-Sn alloy; In xylene;

upstream raw materials:

tin(IV) chloride

tetra(p-tolyl)tin

para-bromotoluene

para-chlorotoluene

Downstream raw materials:

(4-Me-C₆H₄)3Sn(CH₂C₆H₄-4-F)

N(C₂H₅)4⁽¹⁺⁾*{(C₆H₄CH₃)3SnFe(CO)4}^(1-)={N(C₂H₅)4}{(C₆H₄CH₃)3SnFe(CO)4}

(p-CH₃C₆H₄)3SnC₆H₄-m-CF₃

(p-CH₃C₆H₄)3SnCH₃

Refernces

• 1、 Lo, Kong-Mun,Das, V. G. Kumar,Yip, Wai-Hing,Mak, Thomas C. W.. "Organotin esters of 3-ureidopropionic acid. Crystal structure of triphenyltin(IV) 3-ureidopropionate, (C6H5)3SnOCO(CH2)2NHCONH2". . p. 21 - 29. Retrieved 2007/10/02.