{Mn₃O(O₂CPh)6(pyridine)2(H₂O)}*0.5CH₃CN

Base Information

• Chemical Name: {Mn₃O(O₂CPh)6(pyridine)2(H₂O)}*0.5CH₃CN
• CAS No.: 109862-72-8
• Molecular Formula: C₅₂H₄₂Mn₃N₂O₁₄
• Molecular Weight: 1104.25
• Mol file: 109862-72-8.mol

Synonyms:{Mn₃O(O₂CPh)6(pyridine)2(H₂O)}*0.5CH₃CN

Chemical Property of {Mn₃O(O₂CPh)6(pyridine)2(H₂O)}*0.5CH₃CN

Chemical Property:

Purity/Quality:

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Technology Process of {Mn₃O(O₂CPh)6(pyridine)2(H₂O)}*0.5CH₃CN

There total 1 articles about {Mn₃O(O₂CPh)6(pyridine)2(H₂O)}*0.5CH₃CN which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

tetra-n-butylammonium permanganate (35638-41-6) + Mn(O2CCH3)2*4H2O + benzoic acid (65-85-0,8013-63-6) → {Mn3O(O2CPh)6(pyridine)2(H2O)}*0.5CH3CN (109862-72-8)

Guidance literature:

With pyridine; In ethanol; acetic acid; aerobic conditions, Mn compd., acid dissolved in solvent mixture, solid ammonium salt added under stirring,; after 24 h ppt. filtered off, ppt. washed with EtOH, dried in vac., crude yield:>95%; recrystn. by allowing an acetonitrile soln. to slowly concentrate by evapn., ppt. filtered off, washed with EtOH, dried in vac., elem. anal.;

DOI:10.1021/ja00253a023

Reference yield: 82.0%

[Mn3O(benzoato)6(pyridine)2(H2O)] (109862-72-8) + 1-naphthyl phosphonic acid (7402-93-9) + acetonitrile (75-05-8,26809-02-9) → Mn(II)8Mn(III)2O2(C6H5CO2)10(pyridine)4(1-naphthylphosphonic acid(2-))4(H2O)2*4H2O*pyridine*MeCN

Guidance literature:

In acetonitrile; Mn-complex and ligand dissolved in MeCN, stirred for 10 min, transferredinto glass tube, heated with microwave at 120°C for 5 min, coole d; filtered, allowed to stand for 48 h, collected, washed with MeCN, dried in air; elem. anal.;

DOI:10.1039/b901121h

Reference yield: 80.0%

[Mn3O(benzoato)6(pyridine)2(H2O)] (109862-72-8) + ethanol (64-17-5) + water (7732-18-5) → [Mn13O8(OEt)6(benzoate)12]*7H2O

Guidance literature:

With NEt₃; In ethanol; acetonitrile; byproducts: PhCO2H; NEt3 added in small portions to stirred soln. of Mn complex in MeCN-EtOH; stirred for 20 min; filtered; filtrate layered with Et2O; left undisturbed at ambient temp. for 2 d; filtered; crystals washed with Et2O; dried in vac.; elem. anal.;

DOI:10.1021/ic801484g

upstream raw materials:

tetra-n-butylammonium permanganate

benzoic acid

Downstream raw materials:

Mn⁽²⁺⁾*C₆H₅COO^(1-)*C₅H₄NCOO^(1-)*C₅H₄NCHNOH=[Mn(C₆H₅COO)(C₅H₄NCOO)(C₅H₄NCHNOH)]

Refernces