2,17-bis-formyl-5,10,15-tris-(pentafluorophenyl)corrolatogallium(III)(bis-pyridine)

Base Information

Chemical Name:2,17-bis-formyl-5,10,15-tris-(pentafluorophenyl)corrolatogallium(III)(bis-pyridine)
CAS No.:443927-48-8
Molecular Formula:C₄₉H₁₈F₁₅GaN₆O₂
Molecular Weight:1077.42
Hs Code.:

Synonyms:2,17-bis-formyl-5,10,15-tris-(pentafluorophenyl)corrolatogallium(III)(bis-pyridine)

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Chemical Property of 2,17-bis-formyl-5,10,15-tris-(pentafluorophenyl)corrolatogallium(III)(bis-pyridine)

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Technology Process of 2,17-bis-formyl-5,10,15-tris-(pentafluorophenyl)corrolatogallium(III)(bis-pyridine)

There total 3 articles about 2,17-bis-formyl-5,10,15-tris-(pentafluorophenyl)corrolatogallium(III)(bis-pyridine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 322641-60-1
5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine)

: 3-formyl-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine)

: 443927-48-8
2,17-bis-formyl-5,10,15-tris-(pentafluorophenyl)corrolatogallium(III)(bis-pyridine)

Guidance literature:: With DMF; POCl₃; Na₂CO₃; In dichloromethane; N,N-dimethyl-formamide; DMF cooled to 5-10°C, POCl3 added under N2; mixt. stirred for 15 min; ise bath removed; stirred for 15 min; dry CH2Cl2 added; cooled to 0-5°C; resulting soln. (110 mol %) added to Ga-complex in CH2Cl2; satd. soln. of Na2CO3 added; stirred; org. phase sepd.; water phase extd. (CH2Cl2); org. phases combined; washed by brine; dried (Na2SO4); solvent evapd.; column chromd. on SiO2 (CH2Cl2/hexane/pyridine as eluent); recrystd. (CH2Cl2, hexane, some drops ofpyridine);
DOI:10.1021/ja025851g

Reference yield: 9.8%

: 322641-60-1
5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine)

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 443927-48-8
2,17-bis-formyl-5,10,15-tris-(pentafluorophenyl)corrolatogallium(III)(bis-pyridine)

: C₄₃H₁₃F₁₅GaN₅O

Guidance literature:: N,N-dimethyl-formamide; With trichlorophosphate; In dichloromethane; N,N-dimethyl-formamide; for 0.5h; Inert atmosphere; Cooling with ice;

5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine); In dichloromethane; N,N-dimethyl-formamide; for 0.166667h; Inert atmosphere;
DOI:10.1039/c5dt03104d

Reference yield:

: 322641-60-1
5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine)

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 443927-48-8
2,17-bis-formyl-5,10,15-tris-(pentafluorophenyl)corrolatogallium(III)(bis-pyridine)

Guidance literature:: N,N-dimethyl-formamide; With trichlorophosphate; at 20 ℃; Cooling with ice; Inert atmosphere;

5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine); In dichloromethane; at 20 ℃; Cooling with ice; Inert atmosphere;

With potassium carbonate; In water; at 20 ℃; for 12h; Cooling with ice; Inert atmosphere;
DOI:10.1002/anie.201801555