322641-60-1

Basic information

• Product Name: 5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine)
• Synonyms: 5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine)
• CAS NO: 322641-60-1
• Molecular Weight: 942.298
• Mol File: 322641-60-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine)(CAS DataBase Reference)
• NIST Chemistry Reference: 5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine)(322641-60-1)
• EPA Substance Registry System: 5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine)(322641-60-1)

Safety Data

• Hazardous Substances Data: 322641-60-1(Hazardous Substances Data)

Upstream product

• 110-86-1 pyridine 
• 238402-21-6 5,10,15-tris(2,3,4,5,6-pentafluorophenyl)corrole 
• 238402-21-6 5,10,15-tris(pentafluorophenyl)corrole 
• 13450-90-3 Gallium trichloride 

Downstream Products

• 749216-79-3 5,10,15-tris(pentafluorophenyl)corrolate-3-carbaldehyde gallium(III) 
• 443927-48-8 2,17-bis-formyl-5,10,15-tris-(pentafluorophenyl)corrolatogallium(III)(bis-pyridine) 
• 1160558-54-2 [(5,10,15-tris(pentafluorophenyl)corrole)Ga(pyridine)2] 
• 443927-45-5 3,17-dinitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine) 
• 443927-44-4 3-nitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine) 
• 443927-46-6 3,17,18-trinitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine) 

Relevant articles and documents

Evidence for a [17] π-Electronic Full-Fledged Non-innocent Gallium(III)-Corrole Radical

One-electron oxidation of a GaIII-corrole with N(4-BrC6H4)3SbCl6 resulted in an air-stable non-innocent GaIII-corrole radical. The single-crystal X-ray crystallography of the 2,17-bis-formyl-5,10,15-tris(pentafluorophenyl)corrolato gallium(III)(chloride) radical ([3-Cl].) revealed delocalization of the unpaired electron, which was further confirmed by electron spin resonance (ESR) spectroscopy and spin density distribution plot. In addition, the nucleus-independent chemical shift (NICS), anisotropy-induced current density (AICD) and harmonic oscillator model of aromaticity (HOMA) supported a [17] π-electron-conjugated (or antiaromatic) radical.

Gallium(III)corrole-BODIPY hybrid: Novel photophysical properties and first observation of B-F?F interactions

Anchoring a BODIPY onto Ga(iii)corrole via a meso-β linkage facilitated PeT in polar solvents, which quenched the fluorescence, and is further confirmed by electrochemical studies. The triad exhibits unprecedented crystal emission, which is not known for

Corrole-silica hybrid particles: Synthesis and effects on singlet oxygen generation

The present study describes the first example of hybrid particles composed of amorphous silica and corrole. The hybrid particles were obtained by covalent linking of the gallium(iii)(pyridine) complex of 5,10,15-tris(pentafluorophenyl) corrole (GaPFC) at the surface of functionalized silica spheres. The functionalization step was achieved by a nucleophilic substitution reaction between corrole and 3-aminopropyltriethoxysilane previously grafted at the silica surfaces. The hybrids were morphologically and chemically characterized and the results have confirmed covalent linkages between corrole molecules and the silica particles. Preliminary studies on the capacity of corrole and hybrid particles to generate singlet oxygen was evaluated by a chemical method in which 1,3-diphenylisobenzofuran was used to trap singlet oxygen. The new corrole-silica hybrid particles have shown lower efficiency to generate singlet oxygen as compared to the pure corrole precursor. This effect was interpreted as a consequence of interparticle interactions mediated by the corrole molecules grafted at the silica surfaces that result in their clustering. Taken together, these findings demonstrate that despite lower efficiency in terms of singlet oxygen generation, the hybrid materials offer an alternative route to develop new platforms with potential for photodynamic therapy. The Royal Society of Chemistry.