((2S,4R)-4-((4-methoxybenzyloxy)methyl)-2-methylpentyloxy)(tert-butyl)diphenylsilane

Base Information

Chemical Name:((2S,4R)-4-((4-methoxybenzyloxy)methyl)-2-methylpentyloxy)(tert-butyl)diphenylsilane
CAS No.:1417795-87-9
Molecular Formula:C₃₁H₄₂O₃Si
Molecular Weight:490.758
Hs Code.:

Synonyms:((2S,4R)-4-((4-methoxybenzyloxy)methyl)-2-methylpentyloxy)(tert-butyl)diphenylsilane

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Chemical Property of ((2S,4R)-4-((4-methoxybenzyloxy)methyl)-2-methylpentyloxy)(tert-butyl)diphenylsilane

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Technology Process of ((2S,4R)-4-((4-methoxybenzyloxy)methyl)-2-methylpentyloxy)(tert-butyl)diphenylsilane

There total 9 articles about ((2S,4R)-4-((4-methoxybenzyloxy)methyl)-2-methylpentyloxy)(tert-butyl)diphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 105-13-5
4-Methoxybenzyl alcohol

: 157837-64-4
(2R,4S)-5-{[tert-butyl(diphenyl)silyl]oxy}-2,4-dimethylpentan-1-ol

: 1417795-87-9
((2S,4R)-4-((4-methoxybenzyloxy)methyl)-2-methylpentyloxy)(tert-butyl)diphenylsilane

Guidance literature:: 4-Methoxybenzyl alcohol; With sodium hydride; In diethyl ether; at 20 ℃;

With trichloroacetonitrile; In diethyl ether; at 0 - 20 ℃; for 6h;

(2R,4S)-5-{[tert-butyl(diphenyl)silyl]oxy}-2,4-dimethylpentan-1-ol; In dichloromethane; cyclohexane; at 0 - 20 ℃;
DOI:10.1016/j.tet.2012.11.051

Reference yield:

: 1417795-86-8
C₂₃H₃₂O₃Si

: 1417795-87-9
((2S,4R)-4-((4-methoxybenzyloxy)methyl)-2-methylpentyloxy)(tert-butyl)diphenylsilane

Guidance literature:: Multi-step reaction with 4 steps

1.1: 1,8-diazabicyclo[5.4.0]undec-7-ene / tetrahydrofuran / 1 h / Reflux

2.1: lithium aluminium tetrahydride / diethyl ether / 0 °C / Reflux

3.1: Gluconobacter oxydans / 2,2,4-trimethylpentane / 1 h / 20 °C / Enzymatic reaction

4.1: sodium hydride / diethyl ether / 20 °C

4.2: 6 h / 0 - 20 °C

4.3: camphorsulfonic acid / 0 - 20 °C

With lithium aluminium tetrahydride; sodium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; 2,2,4-trimethylpentane; diethyl ether;
DOI:10.1016/j.tet.2012.11.051

Reference yield:

: C₂₃H₃₂O₃Si

: 1417795-87-9
((2S,4R)-4-((4-methoxybenzyloxy)methyl)-2-methylpentyloxy)(tert-butyl)diphenylsilane

Guidance literature:: Multi-step reaction with 3 steps

1.1: lithium aluminium tetrahydride / diethyl ether / 0 °C / Reflux

2.1: Gluconobacter oxydans / 2,2,4-trimethylpentane / 1 h / 20 °C / Enzymatic reaction

3.1: sodium hydride / diethyl ether / 20 °C

3.2: 6 h / 0 - 20 °C

3.3: camphorsulfonic acid / 0 - 20 °C

With lithium aluminium tetrahydride; sodium hydride; In 2,2,4-trimethylpentane; diethyl ether;
DOI:10.1016/j.tet.2012.11.051