C₂H₂N₂(2,6-dimethylbenzene)PPPh₂

Base Information

• Chemical Name: C₂H₂N₂(2,6-dimethylbenzene)PPPh₂
• CAS No.: 905994-36-7
• Molecular Formula: C₃₀H₃₀N₂P₂
• Molecular Weight: 480.529
• Mol file: 905994-36-7.mol

Synonyms:C₂H₂N₂(2,6-dimethylbenzene)PPPh₂

Chemical Property of C₂H₂N₂(2,6-dimethylbenzene)PPPh₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂H₂N₂(2,6-dimethylbenzene)PPPh₂

There total 1 articles about C₂H₂N₂(2,6-dimethylbenzene)PPPh₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

1,3-bis(2,6-dimethylphenyl)-2-chloro-dihydro-1,3,2-diazaphosphole (905994-37-8) + lithium diphenylphosphide (65567-06-8,4541-02-0) → C2H2N2(2,6-dimethylbenzene)PPPh2 (905994-36-7)

Guidance literature:

DOI:10.1039/b605278a

Reference yield: 99.0%

C2H2N2(2,6-dimethylbenzene)PPPh2 (905994-36-7) + borane tetrahydrofuran → C2H2N2(2,6-dimethylbenzene)PPPh2BH3 (1134642-34-4)

Guidance literature:

In benzene-d6; Ar; 1:1 molar mixt., cooled immediately to -10°C;

DOI:10.1002/ejic.200700964

Reference yield: 88.0%

C2H2N2(2,6-dimethylbenzene)PPPh2 (905994-36-7) + carbonyhltungsten(0)(cycloocta-1,5-diene) (12129-70-3) → [(CO)3W(P(C6H5)2)(P(C6H3(CH3)2NCH)2)]2

Guidance literature:

In acetonitrile; W-compd. and P-compd. in CH3CN stirred for 6 h at 50°C, volatilesremoved in vac.; recrystallized at 4°C from THF/toluene, filtered, dried in vac.;

DOI:10.1002/anie.200604622

upstream raw materials:

1,3-bis(2,6-dimethylphenyl)-2-chloro-dihydro-1,3,2-diazaphosphole

lithium diphenylphosphide

Downstream raw materials:

(Z)-2-[1,3-bis-(2',6'-dimethylphenyl)-2,3-dihydro-1H-1,3,2-diazaphospholyl]-3-diphenylphosphanyl-acrylic acid ethyl ester

C₂H₂N₂(2,6-dimethylbenzene)PPPh₂BH₃

1,3-bis(2,6-dimethylphenyl)-2,3-dihydro-1H-1,3,2-diazaphosphole

diphenylphosphane