Polyvinyl chloride

Base Information

• Chemical Name: Polyvinyl chloride
• CAS No.: 9002-86-2
• Molecular Formula: C₂H₃Cl
• Molecular Weight: 62.4988
• Hs Code.: 3904220000
• Mol file: 9002-86-2.mol

Synonyms:Ethylene,chloro-, polymers (8CI);Alkorplan;Alkorplast CCO 13;Allpack;Alpha 30;Alphane AL;Amerace;Amerace A30;Amosu MA 307CL;Aponil 100;Aponil P;Arbosol T 700605;Arbosol T-SP900305;Armodour;Aron 1100;Aron BL 200;Aron BL 2M11VI-P;Aron BL-PL-S2S6G2P;Aron NS 1100;Aron TS 1100;Aron TS 1300;Aron TS 700;Aron TS 800;Aron TS 900;Aron V 500;Aron V 500W16;Aron compound BL;Aron compound HW;Artemis 95A;Arutron GX 446V6;Arutron SSS;Astralon;Atactic PVC;Atacticpoly(vinyl chloride);B 0303CLA;B 0504BLA;B 500 (vinyl polymer);B7021;B 8152;BA 53;BC 718;BCP 57;BCP 59;BCP 65;BCP 66;BFG 110X377;BFG346;BHS;BHS (vinyl polymer);BHST;BK 12S;BK 15 (vinyl polymer);BR530;BS 12K-Fc65234;BS 3503CL7;BVV 0545A;Bakelite OYNV;Bakelite QSAH 7;Bakelite QSAN 7;Bakelite QYAC 10;Bakelite QYJV;Bakelite QYJV 1;BakeliteQYNV 2;Bakelite QYOH;Bakelite QYOH 1;Bakelite QYSJ;Bakelite QYSL 7;Bakelite QYTO 7;Bakelite UCA 3310;Bando 13818;Belbien PR 262;Belbien WA358;Belbien WA 380;Belex XE 770;Benecke 577/E28;Benelit RTF;Benvic;BenvicEB 16;Benvic ER 1525-1A;Benvic IR 047;Blacar 1716;Blacar 1732;Blacar 1738;Blacar 501;Boltaron 6200;Bonloid;Bonset SR 64B;Borden 1071;Borden 26055;Borden TPM 37;Borden VF 71;Bovil Mo 685;Breon 107;Breon 110/10;Breon111EP;Breon 112EP;Breon 113;Breon 121;Breon 125/10;Breon 125/12;Breon130/1;Breon 151;Breon 4001;Breon 4121;Breon 576;Breon M 110/50;Breon M80/50;Breon M 90/50;PVC -P;PVC RESIN;PVC resin SG-5;05NA;1000Z;101EP;1032X;103EP;103EP8;103EP8D;103ZP;108EP;110A;1185PC;1300H;150-255 Natural;168PE;195J;202FRCSA;220L;2500H;28114FC23557;3006-90 Clear 0217;309M;322B;3304WHT194;334FG;37H;37L;380ES;3S Hand;4000M3;40WH91;4763C;57GE-R01;57GERO68;67ER092;6X101Z;70BX;70CQ;725C2H;75BX;84G048A;95A;A 8800;AD 254;AL 30 (polymer);AL 31;AL 4003;AQU 90;AV 32;Adriaplast;Air Lite B 3.75;Air Lite B 6.25;Airco 1230P;Airex;Airex R 63;Airex R 63.50;Airex R 63.80;Polyvinyl chloride;

Chemical Property of Polyvinyl chloride

Chemical Property:

• Appearance/Colour: white or light yellow powder
• Vapor Pressure: 2580mmHg at 25°C
• Melting Point: 170-195 °C (decomp)
• Refractive Index: 1.383
• Boiling Point: 0.100 °C
• PSA: 0.00000
• Density: 1.4 g/mL at 25 °C(lit.)
• LogP: 1.36870
• Storage Temp.: 2-8°C

Purity/Quality:

100% ^*data from raw suppliers

Poly(vinyl chloride) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Description: Polyvinyl chloride, commonly abbreviated PVC, is the thirdmost widely produced plastic, after polyethylene and polypropylene. PVC is used in construction because it is more effective than traditional materials such as copper, iron or wood in pipe and profile applications. It can be made softer and more flexible by the addition of plasticizers, the most widely used being phthalates. In this form, it is also used in clothing and upholstery, electrical cable insulation, inflatable products and many applications in which it replaces rubber. Pure polyvinyl chloride is a white, brittle solid. It is insoluble in alcohol, but slightly soluble in tetrahydrofuran.
• Physical properties: PVC is a thermoplastic polymer. Its properties for PVC are usually categorized based on rigid and flexible PVCs.Mechanical propertiesPVC has high hardness and mechanical properties. The mechanical properties enhance with the molecular weight increasing, but decrease with the temperature increasing. The mechanical properties of rigid PVC (uPVC) is very good, the elastic modulus can reach to 1500-3,000 MPa. The soft PVC (Flexible PVC) elastic is 1.5- 15 MPa. However, elongation at break is up to 200% -450%. PVC friction is ordinary, the static friction factor is 0.4-0.5, the dynamic friction factor is 0.23.Thermal propertiesThe heat stability of PVC is very poor, when the temperature reaches 140 °C PVC starts to decompose. Its melting temperature is 160 °C. The linear expansion coefficient of the PVC is small and has flame retardancy, the oxidation index is up to 45 or more. Therefore, the addition of a heat stabilizer during the process is necessary in order to ensure the product's properties.Electrical propertiesPVC is a polymer with good insulation properties but because of its higher polar nature the electrical insulating property is inferior to non polar polymers such as poly ethylene and poly propylene.
• Uses: Rubber substitutes, electric wire and cable-coverings, pliable thin sheeting, film finishes for textiles, non-flammable upholstery, raincoats, tubing, belting, gaskets, shoe soles. Polyvinyl Chloride could be useful for the removal epoxidation catalyst from epoxidized unsaturated oils. Poly(vinyl chloride), softened with a plasticizer such as esters, is used for making vinyl leather (used for handbags, briefcases, and inexpensive shoes), plastic raincoats, shower curtains, garden hoses, floor covering, and automobile upholstery.

Technology Process of Polyvinyl chloride

There total 187 articles about Polyvinyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-<2-<(2-chloroethyl)sulfinyl>-1,1-dimethylethyl>3-cyclohexyl-1-nitrosourea → thioformaldehyde (865-36-1,30699-99-1) + chloroethylene (75-01-4,9002-86-2) + Cyclohexyl isocyanate (3173-53-3) + 1,3-Dicyclohexylurea (2387-23-7) + acetone (67-64-1)

Guidance literature:

In water; Product distribution; other sulfoxide-substituted nitrosoureas under aqueous decomposition conditions;

DOI:10.1021/ja00339a029

Reference yield:

1-Bromo-2-chloroethane (107-04-0) → chloroethylene (75-01-4,9002-86-2) + hydrogen bromide (10035-10-6,12258-64-9)

Guidance literature:

Reference yield:

1,1,1-trichloroethane (71-55-6,74552-83-3) → dimethylacetylene (503-17-3) + propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + 2,3-dimethylbutene (590-19-2) + chloroethylene (75-01-4,9002-86-2) + chloroacetylene (593-63-5) + acetaldehyde (75-07-0,9002-91-9) + acetic acid (64-19-7,77671-22-8) + prop-1-yne (74-99-7)

Guidance literature:

With vanadium sulfate; water; at 20 ℃; for 0.333333h;

DOI:10.1002/chem.201202918

upstream raw materials:

1,1-dichloroethane

ethene

cis-dichloro(2-chlorovinyl) arsine

1-methyl-4-nitrosobenzene

Downstream raw materials:

vinyltriethylsilane

m-tolyl-vinyl ether

vinyl phenyl ether

p-chlorophenyl vinyl ether

Refernces

• 1、 Fang, Zheng,Feng, Feng,Guo, Lingling,Jin, Chunxiao,Li, Xiaonian,Lu, Jinyue,Pan, Zhiyan,Pang, Xiangxue,Wang, Bolin,Wang, Saisai,Yue, Yuxue,Zhao, Jia. "Acetylene hydrochlorination over supported ionic liquid phase (SILP) gold-based catalyst: Stabilization of cationic Au species via chemical activation of hydrogen chloride and corresponding mechanisms". . p. 334 - 346. Retrieved 2020/07/25.
• 2、 Han, Yong-Jun,Li, Fu-Xiang,Li, Qing-Bin,Li, Song-Tian,Ma, Yao,Wu, Yi-Bo. "Carbon-supported copper–organic framework as active catalysts for acetylene hydrochlorination". . p. 812 - 820. Retrieved 2021/10/05.