((R,E)-1-isocyanato-3-((1S,2S,5R)-2-isopropyl-5-methylcyclohexyl)allyl)-trimethylsilane

Base Information

Chemical Name:((R,E)-1-isocyanato-3-((1S,2S,5R)-2-isopropyl-5-methylcyclohexyl)allyl)-trimethylsilane
CAS No.:881920-77-0
Molecular Formula:C₁₇H₃₁NOSi
Molecular Weight:293.525
Hs Code.:

Synonyms:((R,E)-1-isocyanato-3-((1S,2S,5R)-2-isopropyl-5-methylcyclohexyl)allyl)-trimethylsilane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of ((R,E)-1-isocyanato-3-((1S,2S,5R)-2-isopropyl-5-methylcyclohexyl)allyl)-trimethylsilane

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Technology Process of ((R,E)-1-isocyanato-3-((1S,2S,5R)-2-isopropyl-5-methylcyclohexyl)allyl)-trimethylsilane

There total 9 articles about ((R,E)-1-isocyanato-3-((1S,2S,5R)-2-isopropyl-5-methylcyclohexyl)allyl)-trimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 881920-71-4
(S,E)-1-((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)-3-(trimethylsilyl)allyl carbamate

: 881920-77-0
((R,E)-1-isocyanato-3-((1S,2S,5R)-2-isopropyl-5-methylcyclohexyl)allyl)-trimethylsilane

Guidance literature:: With triethylamine; trifluoroacetic anhydride; In dichloromethane; at 0 ℃; for 0.25h;
DOI:10.1021/ol053061g

Reference yield:

: 881920-95-2
(R,E)-1-((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)-3-(trimethylsilyl)allyl carbamate

: ((S,E)-1-isocyanato-3-((1S,2S,5R)-2-isopropyl-5-methylcyclohexyl)allyl)-trimethylsilane

: 881920-77-0
((R,E)-1-isocyanato-3-((1S,2S,5R)-2-isopropyl-5-methylcyclohexyl)allyl)-trimethylsilane

Guidance literature:: With triethylamine; trifluoroacetic anhydride; In dichloromethane; at 0 ℃; for 0.25h; Title compound not separated from byproducts;
DOI:10.1021/ol053061g

Reference yield:

: 70737-22-3
((E)-2-iodoethenyl)(trimethyl)silane

: 881920-77-0
((R,E)-1-isocyanato-3-((1S,2S,5R)-2-isopropyl-5-methylcyclohexyl)allyl)-trimethylsilane

Guidance literature:: Multi-step reaction with 6 steps

1.1: tert-butyllithium / diethyl ether; pentane / -78 - 23 °C

1.2: 40 percent / diethyl ether; pentane / 3 h / -78 °C

2.1: 67 percent / N-methylmorpholine N-oxide; tetrapropylammonium perruthenate; molecular sieves 4 Angstroem / CH₂Cl₂ / 0.58 h / 20 °C

3.1: lithium triethylborohydride / tetrahydrofuran / 0.33 h / -78 °C

4.1: CH₂Cl₂ / 1 h / 0 °C

5.1: 268 mg / potassium carbonate / methanol; H₂O / 0 - 23 °C

6.1: trifluoroacetic anhydride; triethylamine / CH₂Cl₂ / 0.25 h / 0 °C

With tetrapropylammonium perruthennate; 4 A molecular sieve; tert.-butyl lithium; lithium triethylborohydride; potassium carbonate; 4-methylmorpholine N-oxide; triethylamine; trifluoroacetic anhydride; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; pentane;
DOI:10.1021/ol053061g