Technology Process of bipinnatone A
There total 13 articles about bipinnatone A which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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Multi-step reaction with 5 steps
1.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.5 h
3.1: potassium hydroxide / methanol / 18 h / 20 °C
3.2: 20 °C
4.1: sodium tetrahydroborate; iridium(III) chloride hydrate / acetonitrile
5.1: hydrogenchloride; water / methanol / Reflux
With
hydrogenchloride; sodium tetrahydroborate; iridium(III) chloride hydrate; tetrabutyl ammonium fluoride; water; potassium hydroxide;
In
tetrahydrofuran; methanol; acetonitrile;
2.1: Swern oxidation / 3.1: Aldol condensation;
DOI:10.1016/j.cclet.2011.05.010
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: boron trifluoride diethyl etherate
2.1: potassium carbonate / acetone / 8 h / Reflux
3.1: potassium hydroxide / methanol / 18 h / 20 °C
3.2: 20 °C
4.1: sodium tetrahydroborate; iridium(III) chloride hydrate / acetonitrile
5.1: hydrogenchloride; water / methanol / Reflux
With
hydrogenchloride; sodium tetrahydroborate; iridium(III) chloride hydrate; boron trifluoride diethyl etherate; water; potassium carbonate; potassium hydroxide;
In
methanol; acetone; acetonitrile;
1.1: Friedel Crafts acylation / 3.1: Aldol condensation;
DOI:10.1016/j.cclet.2011.05.010