Cobalt(II) tetraphenylporphyrin

Base Information

• Chemical Name: Cobalt(II) tetraphenylporphyrin
• CAS No.: 14172-90-8
• Molecular Formula: C44H28CoN4
• Molecular Weight: 671.726
• Hs Code.: 29339900
• European Community (EC) Number: 238-018-8
• Mol file: 14172-90-8.mol

Synonyms:14172-90-8;5,10,15,20-Tetraphenyl-21H,23H-porphine cobalt(II);Co(II) meso-Tetraphenylporphine;Cobalt(II) meso-tetraphenylporphine;cobalt(ii) tetraphenylporphyrin;Cobalt(II) TPP;YSWG537;LSZLYWSRWXFMOI-UHFFFAOYSA-N;C2986;C3579;FT-0697656;J-007540;lambda(2)-cobalt(2+) 2,7,12,17-tetraphenyl-21,22,23,24-tetraazapentacyclo[16.2.1.1(3),.1,(1)(1).1(1)(3),(1)]tetracosa-1(20),2,4,6(24),7,9,11,13(22),14,16,18-undecaene-21,23-diide

Chemical Property of Cobalt(II) tetraphenylporphyrin

Chemical Property:

• Appearance/Colour: brown crystals or powder powder
• Melting Point: >300 °C (dec.)
• PSA: 34.58000
• Density: 1.20 g/cm3
• LogP: 6.43780
• Storage Temp.: Inert atmosphere,Room Temperature
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 671.164590
• Heavy Atom Count: 49
• Complexity: 807

Purity/Quality:

98%,99%, ^*data from raw suppliers

Co(II)meso-Tetraphenylporphine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=C3C=CC(=C(C4=NC(=C(C5=CC=C([N-]5)C(=C6C=CC2=N6)C7=CC=CC=C7)C8=CC=CC=C8)C=C4)C9=CC=CC=C9)[N-]3.[Co+2]
• Uses: Co(II) meso-Tetraphenylporphine is used in the decomposition of substituted cycloheptatriene endoperoxides.

Technology Process of Cobalt(II) tetraphenylporphyrin

There total 62 articles about Cobalt(II) tetraphenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + cobalt(II) acetate (71-48-7,917-69-1,5931-89-5,55881-15-7,68931-68-0,68931-69-1,93029-27-7) → cobalt(II) 5,10,15,20-tetraphenylporphyrin (14172-90-8)

Guidance literature:

In N,N-dimethyl-formamide; reflux for 1 h;

DOI:10.1021/om9705315

Reference yield: 94.4%

5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) + cobalt(II) nitrate → cobalt(II) 5,10,15,20-tetraphenylporphyrin (14172-90-8)

Guidance literature:

In ethanol; water; at 90 ℃; for 4h; Inert atmosphere;

DOI:10.1039/c7gc02657a

Reference yield: 92.0%

cobalt(II) acetate (71-48-7,917-69-1,5931-89-5,55881-15-7,68931-68-0,68931-69-1,93029-27-7) + 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → cobalt(II) 5,10,15,20-tetraphenylporphyrin (14172-90-8)

Guidance literature:

In N,N-dimethyl-formamide; at 110 ℃; for 1h; Inert atmosphere;

DOI:10.1021/ma301205g

upstream raw materials:

5,10,15,20-tetraphenyl-21H,23H-porphine

cobalt(II) acetate

cobalt(II) diacetate tetrahydrate

chloro(5,10,15,20-tetraphenylporphyrinato)cobalt(III)

Downstream raw materials:

[5,10,15,20-tetraphenylporphyrin]cobalt(III) chloride

ferrocenium

(5,10,15,20-tetraphenylporphyrinato)cobalt(III)⁽¹⁺⁾

nitrosylcobalt(II) meso-tetraphenylporphyrinate

Refernces

Synthesis and chemistry of unusual bicyclic endoperoxides containing the pyridazine ring

10.1021/jo0345300

The study focuses on the synthesis and chemical transformations of unusual bicyclic endoperoxides containing the pyridazine ring, which are significant due to their potential synthetic applications and pharmacological activities, particularly in cardiovascular systems. The researchers utilized various chemicals, including dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate, unsaturated bicyclic endoperoxides, NEt3 (triethylamine), CoTPP (cobalt(II) tetraphenylporphyrin), and thiourea. These chemicals served as reactants, catalysts, and reductants in the synthesis of bicyclic endoperoxides and their subsequent transformations into pyridazine derivatives and other heterocyclic compounds. The study aimed to develop a method for accessing these complex molecules and explore the diverse chemical reactions of the peroxide functional group within them.