Technology Process of nitrosyl(5,10,15,20-tetraphenylporphyrinato)(pyridine)cobalt(III)
There total 5 articles about nitrosyl(5,10,15,20-tetraphenylporphyrinato)(pyridine)cobalt(III) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
pyridine;
In
acetonitrile;
byproducts: Ag; suspn. of complex is treated with pyridine and AgNO2 under N2, reflux for 7 h; filtn. in air, ppt. is washed with MeCN and then extd. with CH2Cl2, extract is evapd., identified by comparison of IR and (1)H-NMR spectra withan authentic sample;
DOI:10.1021/om00121a012
- Guidance literature:
-
With
pyridine; oxygen;
In
dichloromethane;
O2 bubbling into soln. of Co(TPP)NO for 4 h, addn. of petroleum ether-hexane (1:1), pptn.; filtration, washing with hexane, drying under vac. at room temp., elem.anal.;
DOI:10.1021/ja00402a044
- Guidance literature:
-
With
O2;
In
toluene;
air oxidation of complex in toluene in the presence of excess pyridine; Kaduk, J. A.; Scheidt, W. R. Inorg. Chem. 1974, 13, 1875-1880; chromy. on silica gel (toluene; 10% soln. of methanol in toluene);
DOI:10.1021/ic001442e
