phenyldichlorocarbonylbis(triphenylphosphine)rhodium(III)

Base Information

• Chemical Name: phenyldichlorocarbonylbis(triphenylphosphine)rhodium(III)
• CAS No.: 52438-22-9
• Molecular Formula: C₄₃H₃₅Cl₂OP₂Rh
• Molecular Weight: 803.509
• Mol file: 52438-22-9.mol

Synonyms:phenyldichlorocarbonylbis(triphenylphosphine)rhodium(III)

Chemical Property of phenyldichlorocarbonylbis(triphenylphosphine)rhodium(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenyldichlorocarbonylbis(triphenylphosphine)rhodium(III)

There total 2 articles about phenyldichlorocarbonylbis(triphenylphosphine)rhodium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

tris(triphenylphosphine)rhodium(l) chloride (14694-95-2) + benzoyl chloride (98-88-4) → phenyldichlorocarbonylbis(triphenylphosphine)rhodium(III) (52438-22-9)

Guidance literature:

In benzene; addn. of freshly distd. benzoylchloride to a soln. of Rh-complex under N2, stirring at 80°C for 30 min; quenching by addn. of pentane, filtn. of yellow ppt., washing (Et2O), drying under vac.;

DOI:10.1021/ja00294a031

Reference yield:

Wilkinson's catalyst (14694-95-2) + benzoyl chloride (98-88-4) → chlorocarbonylbis(triphenylphosphine)rhodium(I) (15318-33-9,16353-77-8,13938-94-8) + phenyldichlorocarbonylbis(triphenylphosphine)rhodium(III) (52438-22-9) + chlorobenzene (108-90-7)

Guidance literature:

80°C, excess benzoyl chloride, 15 min;

DOI:10.1021/ja00397a049

Reference yield:

phenyldichlorocarbonylbis(triphenylphosphine)rhodium(III) (52438-22-9) + benzoyl chloride (98-88-4) → chlorocarbonylbis(triphenylphosphine)rhodium(I) (15318-33-9,16353-77-8,13938-94-8) + phenyldichlorobis(triphenylphosphine)rhodium(III) (94859-70-8)

Guidance literature:

With carbon monoxide; In further solvent(s); 80-111°C (in boiling benzene, dichloroethane or toluene) in presence of air or N2; sepn. by chromy. on silica gel;

DOI:10.1021/ja00397a049

upstream raw materials:

Wilkinson's catalyst

benzoyl chloride

tris(triphenylphosphine)rhodium(l) chloride

Downstream raw materials:

chlorocarbonylbis(triphenylphosphine)rhodium(I)

phenyldichlorobis(triphenylphosphine)rhodium(III)