1,2-Bis(diphenylphosphino)propane

Base Information

• Chemical Name: 1,2-Bis(diphenylphosphino)propane
• CAS No.: 15383-58-1
• Molecular Formula: C27H26 P2
• Molecular Weight: 412.451
• Hs Code.: 2902909090
• DSSTox Substance ID: DTXSID30394560
• Nikkaji Number: J1.226.306F
• ChEMBL ID: CHEMBL69493
• Mol file: 15383-58-1.mol

Synonyms:15383-58-1;1,2-BIS(DIPHENYLPHOSPHINO)PROPANE;1,2-bis-(diphenylphosphino)propane;1-diphenylphosphanylpropan-2-yl(diphenyl)phosphane;Propane-1,2-diylbis(diphenylphosphine);[(2R)-1-diphenylphosphanylpropan-2-yl]-diphenylphosphane;dppip;[(2S)-1-diphenylphosphanylpropan-2-yl]-diphenylphosphane;CHEMBL69493;SCHEMBL613867;DTXSID30394560;WGOBPPNNYVSJTE-UHFFFAOYSA-N;FT-0641151;FT-0771250

Chemical Property of 1,2-Bis(diphenylphosphino)propane

Chemical Property:

• Boiling Point: 521.9±33.0 °C(Predicted)
• PSA: 27.18000
• LogP: 5.64070
• XLogP3: 6.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 7
• Exact Mass: 412.15097482
• Heavy Atom Count: 29
• Complexity: 404

Purity/Quality:

98% ^*data from raw suppliers

1,2-BIS(DIPHENYLPHOSPHINO)PROPANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(CP(C1=CC=CC=C1)C2=CC=CC=C2)P(C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of 1,2-Bis(diphenylphosphino)propane

There total 4 articles about 1,2-Bis(diphenylphosphino)propane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

1,2-Dibromopropane (78-75-1) + diphenylphosphane (829-85-6) → 1,2-bis(diphenylphosphino)propane (15383-58-1,67884-33-7)

Guidance literature:

diphenylphosphane; With cesiumhydroxide monohydrate; In N,N-dimethyl-formamide; at 20 ℃; for 1h; Molecular sieve; Inert atmosphere;

1,2-Dibromopropane; In N,N-dimethyl-formamide; at 20 ℃; for 72h; Inert atmosphere; Molecular sieve;

Reference yield:

1,2-propanediene (463-49-0) + diphenylphosphane (829-85-6) → 1,3-bis-(diphenylphosphino)propane (6737-42-4) + 1,2-bis(diphenylphosphino)propane (15383-58-1,67884-33-7) + Diphenylphosphine oxide (4559-70-0) + allyldiphenylphosphine (2741-38-0)

Guidance literature:

for 8h; Irradiation;

DOI:10.1016/0022-328X(91)86141-C

Reference yield:

1,2-propanediol bismesylate (26439-20-3) + lithium diphenylphosphide (65567-06-8,4541-02-0) → 1,2-bis(diphenylphosphino)propane (15383-58-1,67884-33-7)

Guidance literature:

In tetrahydrofuran; at -78 - 20 ℃; Schlenk technique;

DOI:10.1021/cs400651h

upstream raw materials:

1,2-propanediene

diphenylphosphane

1,2-Dibromopropane

1,2-propanediol bismesylate

Downstream raw materials:

cis[PtPh₂(1,2-bis(diphenylphosphanyl)propane)]

cobalt[1,3-bis(diphenylphosphino)propane] dibromide

[Pd(NO₂)2((C₆H₅)2P)2(CH₂)3]

[Pd(NO₂)2((C₆H₅)2P)2(CH₂)3]

Refernces

The synthesis of novel neutral mononuclear ruthenium fragments for cluster capping reactions and their reactivity

10.1016/S0022-328X(97)00384-7

The research explores the generation of reactive mononuclear ruthenium fragments through photochemistry and their subsequent use in cluster capping reactions. Key chemicals involved include [Ru3(CO)12] (2), [Ru5C(CO)15] (4), and various bidentate phosphines such as 1,2-bis(diphenylphosphino)propane (dppp). The mononuclear complex [Ru(CO)4(C2H4)] (1) was generated by photolysis of [Ru3(CO)12] in the presence of ethylene and was found to be unsuitable for cluster capping due to its tendency to trimerise back to [Ru3(CO)12]. To address this, bidentate phosphines were used to anchor the mononuclear ruthenium fragments, resulting in the formation of complexes like [Ru(CO)4(η1-dppp)] (3d). These complexes showed potential in selective cluster capping reactions, as demonstrated by their reactivity with [Ru5C(CO)15] to form bridged cluster-mononuclear complexes such as [Ru5C(CO)14(η1,η1-dppp)Ru(CO)4] (5d). Further studies involved the formation of di-substituted complexes like [Ru(CO)3(η1-dppp)(η2-C2H4)] (9d) and their reactivity with clusters, yielding products such as [Ru6C(CO)16(μ2-dppp)] (7d). The research highlights the use of photochemistry to generate novel ruthenium fragments and their application in creating specific cluster products, offering new routes to known and previously unreported mononuclear ruthenium complexes.

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 15383-58-1 1,2-Bis-(diphenylphosphino)propane

Send

Send

Metric Ton KG G Pound L ML

Send

Send