N-[2,6-bis(propan-2-yl)phenyl]-1-(thiophen-2-yl)methanimine

Base Information

• Chemical Name: N-[2,6-bis(propan-2-yl)phenyl]-1-(thiophen-2-yl)methanimine
• CAS No.: 187605-54-5
• Molecular Formula: C₁₇H₂₁NS
• Molecular Weight: 271.426
• Mol file: 187605-54-5.mol

Synonyms:N-[2,6-bis(propan-2-yl)phenyl]-1-(thiophen-2-yl)methanimine

Chemical Property of N-[2,6-bis(propan-2-yl)phenyl]-1-(thiophen-2-yl)methanimine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-[2,6-bis(propan-2-yl)phenyl]-1-(thiophen-2-yl)methanimine

There total 1 articles about N-[2,6-bis(propan-2-yl)phenyl]-1-(thiophen-2-yl)methanimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

thiophene-2-carbaldehyde (98-03-3) + 2,6-diisopropylbenzenamine (24544-04-5) → N-[2,6-bis(propan-2-yl)phenyl]-1-(thiophen-2-yl)methanimine (187605-54-5)

Guidance literature:

With formic acid; In ethanol; at 20 ℃; for 4h; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.molstruc.2018.06.075

Reference yield: 87.0%

sodium tetrachloropalladate(II) + N-[2,6-bis(propan-2-yl)phenyl]-1-(thiophen-2-yl)methanimine (187605-54-5) → trans-dichlorobis(2,6-diisopropyl-N-(2-thienylmethylidene)aniline)palladium(II)

Guidance literature:

With NaCH₃COO; In methanol; inert atmosphere using standard Schlenk techniques; soln. of Na2PdCl2, ligand and NaOAc (1:2:2 mol) stirred at room temp. for 6 h; product filtered off; washed (H2O, Et2O); dissolved in CH2Cl2; soln. filtered; filtrate evapd.; residue crystd. (CH2Cl2/hexane); elem. anal.;

DOI:10.1016/j.ica.2011.06.003

Reference yield: 42.0%

thallium(I) hexafluorophosphate (60969-19-9) + bi(allylnickel bromide) + N-[2,6-bis(propan-2-yl)phenyl]-1-(thiophen-2-yl)methanimine (187605-54-5) → [Ni(η3-allyl)(2,6-diisopropyl-N-(thiophen-2-ylmethylene)aniline)2][PF6]

Guidance literature:

bi(allylnickel bromide); N-[2,6-bis(propan-2-yl)phenyl]-1-(thiophen-2-yl)methanimine; In dichloromethane; at 0 ℃; Schlenk technique; Inert atmosphere;

thallium(I) hexafluorophosphate; In dichloromethane; at 20 ℃; for 1h; Schlenk technique; Inert atmosphere;

DOI:10.1016/j.molstruc.2018.06.075

upstream raw materials:

thiophene-2-carbaldehyde

2,6-diisopropylbenzenamine