methyl 3-oxo-3-phenylpropanedithioate

Base Information

• Chemical Name: methyl 3-oxo-3-phenylpropanedithioate
• CAS No.: 20365-21-3
• Molecular Formula: C₁₀H₁₀OS₂
• Molecular Weight: 210.321
• Mol file: 20365-21-3.mol

Synonyms:methyl 3-oxo-3-phenylpropanedithioate

Chemical Property of methyl 3-oxo-3-phenylpropanedithioate

Chemical Property:

• Melting Point: 57-58 °C
• Boiling Point: 348.8±25.0 °C(Predicted)
• Density: 1.216±0.06 g/cm3(Predicted)

Purity/Quality:

99% ，98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 3-oxo-3-phenylpropanedithioate

There total 3 articles about methyl 3-oxo-3-phenylpropanedithioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

→ methyl 3-oxo-3-phenylpropanedithioate (20365-21-3)

Guidance literature:

Reference yield: 72.0%

(S,S)-dimethyl trithiocarbonate (2314-48-9) + acetophenone (98-86-2) → methyl 3-oxo-3-phenylpropanedithioate (20365-21-3)

Guidance literature:

With sodium hydride; In hexane; N,N-dimethyl-formamide; at 20 ℃;

DOI:10.1021/jo101572c

Reference yield: 67.0%

3,3-bis(methylthio)-1-phenylprop-2-en-1-one (13636-88-9) → methyl 3-oxo-3-phenylpropanedithioate (20365-21-3)

Guidance literature:

With boron trifluoride diethyl etherate; hydrogen sulfide; In 1,4-dioxane; for 3h; Heating;

DOI:10.1080/00397919908086034

upstream raw materials:

(S,S)-dimethyl trithiocarbonate

acetophenone

3,3-bis(methylthio)-1-phenylprop-2-en-1-one

Downstream raw materials:

methyl 3-(4-methylphenyl)-3-oxopropanedithioate

2-(Bis-methylsulfanyl-methylene)-4-methyl-1-phenyl-pent-4-en-1-one

3-(3aR,6aR)-Hexahydro-cyclopenta[b]pyrrol-1-yl-1-phenyl-3-thioxo-propan-1-one

(2R,3aR,6aR)-1-(3-Oxo-3-phenyl-thiopropionyl)-octahydro-cyclopenta[b]pyrrole-2-carboxylic acid benzyl ester