caesium fluorosulfate

Base Information

• Chemical Name: caesium fluorosulfate
• CAS No.: 13530-70-6
• Molecular Formula: Cs*FO₃S
• Molecular Weight: 231.968
• Mol file: 13530-70-6.mol

Synonyms:caesium fluorosulfate

Chemical Property of caesium fluorosulfate

Chemical Property:

Purity/Quality:

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Technology Process of caesium fluorosulfate

There total 1 articles about caesium fluorosulfate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cesium fluorosulfite (15857-38-2) → sulfur (10544-50-0) + caesium fluorosulfate (13530-70-6) + cesium fluoride (13400-13-0)

Guidance literature:

In neat (no solvent); heating under > 200 hPa SO2;

DOI:10.1021/ic970315o

Reference yield: 99.0%

antimony (7440-36-0) + caesium fluorosulfate (13530-70-6) + bis(fluorosulfuryl) peroxide (13709-32-5) → cesium hexakis(fluorosulfato)antimonate(V)

Guidance literature:

In fluorosulphonic acid; eqimolar amts. of CsSO3F and Sb, excess of peroxide (25°C, 12 h); slow evapn. of volatiles (crystn.);

Reference yield: 77.0%

niobium + caesium fluorosulfate (13530-70-6) + bis(fluorosulfuryl) peroxide (13709-32-5) → Cs(1+)*Nb(SO3F)6(1-)=Cs{Nb(SO3F)6}

Guidance literature:

With HSO₃F; In fluorosulphonic acid; niobium metal powder added to CsSO3F, addn. of S2O6F2 and HSO3F, stirred at room temp. for 2 days; powder collected by vac. filtration, excess S2O6F2 removed , dried for 24 h at room temp. (vac.), elem. anal.;

DOI:10.1021/ja00194a026

upstream raw materials:

cesium fluorosulfite

Refernces