N,N'-bis[6-(4-iodobenzoylamino)pyridin-2-yl]-1,1'-ferrocenedicarboxylic amide

Base Information

Chemical Name:N,N'-bis[6-(4-iodobenzoylamino)pyridin-2-yl]-1,1'-ferrocenedicarboxylic amide
CAS No.:478811-98-2
Molecular Formula:C₃₆H₂₆FeI₂N₆O₄
Molecular Weight:916.296
Hs Code.:

Synonyms:N,N'-bis[6-(4-iodobenzoylamino)pyridin-2-yl]-1,1'-ferrocenedicarboxylic amide

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Chemical Property of N,N'-bis[6-(4-iodobenzoylamino)pyridin-2-yl]-1,1'-ferrocenedicarboxylic amide

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Technology Process of N,N'-bis[6-(4-iodobenzoylamino)pyridin-2-yl]-1,1'-ferrocenedicarboxylic amide

There total 1 articles about N,N'-bis[6-(4-iodobenzoylamino)pyridin-2-yl]-1,1'-ferrocenedicarboxylic amide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 189307-14-0
bis(6-aminopyridin-2-yl)-1,1'-ferrocenedicarboxylic amide

: 619-58-9
4-iodobenzoic acid

: 478811-98-2
N,N'-bis[6-(4-iodobenzoylamino)pyridin-2-yl]-1,1'-ferrocenedicarboxylic amide

Guidance literature:: With oxalyl dichloride; triethylamine; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; (Ar); addn. of (COCl)2 and DMF to soln. of IC6H4COOH in CH2Cl2; stirringfor 1 h at 20°C; removal of solvent under reduced pressure, redi ssolving in THF, addn. of Fe(C5H4CONHC5H3NNH2)2 and Et3N in THF; stirring at 20°C for 18 h; removal of solvent under reduced pressure, addn. of ethyl acetate; washing of org. phase with H2O, extn. of aq. phase once with EtOAc, drying ofcombining org. phase (Na2SO4); evapn. to dryness under vac., chromy. (e thyl acetate/C5H12, 1:1); elem. anal.;
DOI:10.1021/om020364v

Reference yield: 55.0%

: 478811-98-2
N,N'-bis[6-(4-iodobenzoylamino)pyridin-2-yl]-1,1'-ferrocenedicarboxylic amide

: 829-85-6
diphenylphosphane

: 478811-99-3
N,N'-bis[6-(4-(diphenylphosphanyl)benzoylamino)pyridin-2-yl]-1,1'-ferrocenedicarboxylic amide

Guidance literature:: With palladium diacetate; triethylamine; In acetonitrile; (Ar); addn. of Et3N, Ph2PH and soln. of Pd(OAc)2 in CH3CN to soln. of Fe(C5H4CONHC5H3NNHCOC6H4I)2 in CH3CN; warming to 85°C in a closed tube ; stirring for 2 h; cooling, pouring into a separatory flask with CH2Cl2; washing of org. phase with satd. soln. of NH4Cl, drying (Na2SO4); evapn. to dryness under vac., chromy., (CH2Cl2/MeOH, 60:1), elem. anal.;
DOI:10.1021/om020364v