(η5-pentadienyl)ruthenium(bis(triphenylphosphine))chloride

Base Information

• Chemical Name: (η5-pentadienyl)ruthenium(bis(triphenylphosphine))chloride
• CAS No.: 110140-35-7
• Molecular Formula: C₄₁H₃₇ClP₂Ru
• Molecular Weight: 728.215
• Mol file: 110140-35-7.mol

Synonyms:(η5-pentadienyl)ruthenium(bis(triphenylphosphine))chloride

Chemical Property of (η5-pentadienyl)ruthenium(bis(triphenylphosphine))chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η5-pentadienyl)ruthenium(bis(triphenylphosphine))chloride

There total 3 articles about (η5-pentadienyl)ruthenium(bis(triphenylphosphine))chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

hydridochlorotris(triphenylphosphine)ruthenium(II) (55102-19-7) + 1,4-Pentadiene (591-93-5) → (η5-pentadienyl)ruthenium(bis(triphenylphosphine))chloride (110140-35-7)

Guidance literature:

In acetone; stirred (room temp., 6 h); refluxed (6 h);

DOI:10.1016/0022-328X(86)80332-1

Reference yield:

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + pentadienyltributyltin (87920-24-9) → (η5-pentadienyl)ruthenium(bis(triphenylphosphine))chloride (110140-35-7)

Guidance literature:

In tetrahydrofuran; Addn. of Sn-compd. to THF soln. of Ru-complex (N2) and refluxing (1 h) yields a bright orange soln.; Removal of THF (vac.) gives oily orange solid which is taken up in Et2O and passed through on alumina column. Removal of Et2O (vac.), vigorous washing of oil (pentane), drying, filtn., crystn. from Et2O, elem. anal.;

DOI:10.1021/om00101a013

Reference yield:

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + tributyl(penta-2,4-dienyl)stannane (87920-24-9) → (η5-pentadienyl)ruthenium(bis(triphenylphosphine))chloride (110140-35-7)

Guidance literature:

In tetrahydrofuran; Inert atmosphere; Schlenk technique;

DOI:10.1021/om300657z

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

pentadienyltributyltin

hydridochlorotris(triphenylphosphine)ruthenium(II)

1,4-Pentadiene

Downstream raw materials:

(η5-pentadienyl)ruthenium(chloride)(trimethylphosphine)(triphenylphosphine)

(η5-pentadienyl)ruthenium(chloride)(triethylphosphine)(triphenylphosphine)

(η5-pentadienyl)ruthenium(chloride)(diethylphenylphosphine)2

(η5-pentadienyl)ruthenium(chloride)(diethylphenylphosphine)(triphenylphosphine)