(1'S,2'S,5'R)-6',6'-dimethylbicyclo<3.1.1>hept-2'-ylacetaldehyde

Base Information

• Chemical Name: (1'S,2'S,5'R)-6',6'-dimethylbicyclo<3.1.1>hept-2'-ylacetaldehyde
• CAS No.: 109062-93-3
• Molecular Formula: C₁₁H₁₈O
• Molecular Weight: 166.263
• Mol file: 109062-93-3.mol

Synonyms:(1'S,2'S,5'R)-6',6'-dimethylbicyclo<3.1.1>hept-2'-ylacetaldehyde

Chemical Property of (1'S,2'S,5'R)-6',6'-dimethylbicyclo<3.1.1>hept-2'-ylacetaldehyde

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1'S,2'S,5'R)-6',6'-dimethylbicyclo<3.1.1>hept-2'-ylacetaldehyde

There total 3 articles about (1'S,2'S,5'R)-6',6'-dimethylbicyclo<3.1.1>hept-2'-ylacetaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

Beta-pinene (177698-19-0,25719-60-2) + carbon monoxide (201230-82-2) → Pinene (80-56-8,177698-18-9,25766-18-1) + endo-6,6-dimethylbicyclo<3.1.1>hept-2-ylacetaldehyde (60244-27-1,60244-28-2,109062-93-3,109062-94-4,64773-71-3)

Guidance literature:

With hydrogen; In toluene; at 80 ℃; for 24h; under 30402 Torr; Catalytic behavior; Autoclave;

DOI:10.1002/cctc.201600070

Reference yield:

carbon monoxide (201230-82-2) + (-)-α-pinene (25766-18-1) → endo-6,6-dimethylbicyclo<3.1.1>hept-2-ylacetaldehyde (60244-27-1,60244-28-2,109062-93-3,109062-94-4,64773-71-3) + (+)-3-formylpinane (60113-43-1) + formyl pinane

Guidance literature:

With acetylacetonatodicarbonylrhodium(l); C₅₀H₅₉Fe₂NP₂; hydrogen; In toluene; at 120 ℃; for 16h; under 56255.6 Torr;

DOI:10.1021/om300061d

Reference yield:

carbon monoxide (201230-82-2) + beta-pinene (18172-67-3,19902-08-0,25719-60-2) → Pinene (80-56-8,177698-18-9,25766-18-1) + endo-6,6-dimethylbicyclo<3.1.1>hept-2-ylacetaldehyde (60244-27-1,60244-28-2,109062-93-3,109062-94-4,64773-71-3)

Guidance literature:

With triphenyl phosphite; (acetylacetonato)dicarbonylrhodium (l); hydrogen; In butanone; at 99.84 ℃; for 3.3h; under 31053.1 Torr; Inert atmosphere; Autoclave;

DOI:10.14233/ajchem.2019.21656

upstream raw materials:

Beta-pinene

carbon monoxide

(-)-α-pinene

beta-pinene

Downstream raw materials:

((1S,2S)-6,6-dimethyl-norpinan-2-yl)-acetic acid