Re(CO)5(CH₃CN)⁽¹⁺⁾

Base Information

Chemical Name:Re(CO)5(CH₃CN)⁽¹⁺⁾
CAS No.:29421-17-8
Molecular Formula:C₇H₃NO₅Re
Molecular Weight:367.312
Hs Code.:

Re(CO)5(CH<sub>3</sub>CN)<sup>(1+)</sup>

Synonyms:Re(CO)5(CH₃CN)⁽¹⁺⁾

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Re(CO)5(CH₃CN)⁽¹⁺⁾

Chemical Property:

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Technology Process of Re(CO)5(CH₃CN)⁽¹⁺⁾

There total 6 articles about Re(CO)5(CH₃CN)⁽¹⁺⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 14285-68-8
decacarbonyldirhenium⁽⁰⁾

: 14099-01-5
rhenium(I) pentacarbonyl chloride

: 29421-17-8
Re(CO)5(CH₃CN)⁽¹⁺⁾

Guidance literature:: With chlorine; acetonitrile; In acetonitrile; byproducts: Cl(1-); CH3CN was bubbled with Cl2 for 1 min with stirring at room temp.; soln. was evac., sovent was removed under reduced pressure, ant the volatile Re2(CO)5Cl was sublimed from the crude react. residue at 80°C, subimation was continued for 2h, analysis by IR, UV; Kinetics;
DOI:10.1021/ja00317a023

Reference yield:

: 14285-68-8
decacarbonyldirhenium⁽⁰⁾

: 14099-01-5
rhenium(I) pentacarbonyl chloride

: 13821-00-6
rhenium pentacarbonyl iodide

: 29421-17-8
Re(CO)5(CH₃CN)⁽¹⁺⁾

Guidance literature:: With iodine; chlorine; acetonitrile; In acetonitrile; CH3CN was degassed and ICL (27 Torr, 25°C) was vac. transferred into the react.mixt. at -196°C, wasmed to 25°C; detected by IR, the initial Re(CO)5I slowly reacts with excess ICl to Re(CO)5Cl; Kinetics;
DOI:10.1021/ja00317a023

Reference yield:

: 14285-68-8
decacarbonyldirhenium⁽⁰⁾

: 75-05-8,26809-02-9
acetonitrile

: 14099-01-5
rhenium(I) pentacarbonyl chloride

: 29421-17-8
Re(CO)5(CH₃CN)⁽¹⁺⁾

Guidance literature:: With iron(III) chloride; In acetonitrile; Schlenk flask, N2; the decacarbonyl is added to MeCN, oxidant (2 equiv)is added and stirred until dissolved; IR, UV; Kinetics;
DOI:10.1016/S0020-1693(00)96022-5