Rhenium,pentacarbonyl(pentacarbonylmanganese)-, (Mn-Re)

Base Information

• Chemical Name: Rhenium,pentacarbonyl(pentacarbonylmanganese)-, (Mn-Re)
• CAS No.: 14693-30-2
• Molecular Formula: C10Mn O10 Re
• Molecular Weight: 521.249
• Mol file: 14693-30-2.mol

Synonyms:Manganese,pentacarbonyl(pentacarbonylrhenium)- (7CI); Rhenium,pentacarbonyl(pentacarbonylmanganio)- (8CI); Manganese,pentacarbonyl(pentacarbonylrhenio)- (8CI); Decacarbonylmanganeserhenium;Manganese rhenium carbonyl (MnRe(CO)10)

Chemical Property of Rhenium,pentacarbonyl(pentacarbonylmanganese)-, (Mn-Re)

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Rhenium,pentacarbonyl(pentacarbonylmanganese)-, (Mn-Re)

There total 8 articles about Rhenium,pentacarbonyl(pentacarbonylmanganese)-, (Mn-Re) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

rhenium(I) pentacarbonyl bromide (14220-21-4) + dimanganese decacarbonyl (10170-69-1) → decacarbonyldirhenium(0) (14285-68-8) + decacarbonylmanganeserhenium (14693-30-2)

Guidance literature:

With Na#Hg; In tetrahydrofuran; Mn2(CO)10 was treated with sodium amalgam (room temp., N2, 45 min); after removing of amalgam Re complex soln. was added dropwise (30 min); evapn., sublimation;

Reference yield: 58.0%

Li(1+)*ReMn(CO)9(CHO)(1-)=Li(ReMn(CO)9(CHO)) (85283-42-7) + benzaldehyde (100-52-7) → decacarbonylmanganeserhenium (14693-30-2) + benzyl alcohol (100-51-6,185532-71-2)

Guidance literature:

In tetrahydrofuran; under N2, benzaldehyde was added to soln. of Re-Mn-complex in THF at -78°C, warmed to -30°C, 5 min, quenched with aq. THF;

Reference yield: 39.0%

Li(1+)*ReMn(CO)9(CHO)(1-)=Li(ReMn(CO)9(CHO)) (85283-42-7) + triphenyltin chloride (639-58-7) → decacarbonylmanganeserhenium (14693-30-2) + (CO)5ReSn(C6H5)3 (15614-21-8) + triphenyltinmanganesepentacarbonyl (14405-84-6)

Guidance literature:

In tetrahydrofuran; under N2, soln. of Re-Mn-complex in THF was stirred for 5 h at room temp., cooled to -78°C, Ph3SnCl was added, warmed to room temp.; solvent removed by rotary evapn., chromd. on silica gel with ethyl acetate-hexane, solvent removed by rotary evapn., sublimed at 50°C, residue dissolved in hot hexane, placed in freezer overnight;

upstream raw materials:

rhenium(I) pentacarbonyl bromide

bis(triphenylphosphineiminium) pentacarbonylmanganate^(1-)

(Re(CO)6)⁽¹⁺⁾*BF₄^(1-)=(Re(CO)6)(BF₄)

[bis(triphenylphospine)nitrogen⁽¹⁺⁾][Re(CO)5]

Downstream raw materials:

decacarbonyldirhenium⁽⁰⁾

dimanganese decacarbonyl

bis(triphenylphosphineiminium) pentacarbonylmanganate^(1-)

closo-Fe3(CO)9(μ3-SnRe(CO)5)2